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ESR study of the reaction of substituted nitrosobenzenes with aliphatic and saturated alkylaromatic hydrocarbons

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Abstract

We have found that nitrosobenzenes spontaneously react with saturated hydrocarbons in the absence of oxygen and light. For interpretation of this general phenomenon a new reaction pathway has been assumed. In light of these results special care should be taken when applying nitrosobenzenes for inhibition and spin trapping as well as organic synthesis in saturated organic solvents, which are supposed to be inert.

Abstract

Бьло найдено, что в отсутствии кислорода и света насыщенные углеводороды самопроизвольно реагируют с нитрозобензолами. Для интерпретации этого общего явления было предположено новое направление реакции. В свете полученных данных следует обращатя особое внимание при интерпретации экспериментальных результатов в случае применения нитрозобензолов в качестве спиновых ловушек, ингибиторов, а также для синтетических целей при проведении опытов в насыщенных углеводродах как растворителях, которые, по предположению являются инертными.

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Authors and Affiliations

  1. Central Research Institute for Chemistry of the Hungarian Academy of Sciences, P. O. Box 17, H-1525, Budapest, Hungary

    P. Simon, L. Sümegi, A. Rockenbauer, I. Nemes & F. Tüdős

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  1. P. Simon
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  2. L. Sümegi
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  3. A. Rockenbauer
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  4. I. Nemes
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  5. F. Tüdős
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Simon, P., Sümegi, L., Rockenbauer, A. et al. ESR study of the reaction of substituted nitrosobenzenes with aliphatic and saturated alkylaromatic hydrocarbons. React Kinet Catal Lett 15, 493–500 (1981). https://doi.org/10.1007/BF02074155

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  • DOI: https://doi.org/10.1007/BF02074155

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