Skip to main content
SpringerLink
Log in

Reactivity of the CCl3CH2CH .2 radical in processes of homo-and cotelomerization of olefins with carbon tetrachloride

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

From the kinetic studies of CCl3CH2CH2Br addition to 1-hexene, the rate constant of addition of the CCl3CH2CH .2 ( 1e R) radical to 1-hexene [1g 1e kh=(5.2±0.1)−(13 000±800)/RT] has been determined. From the cotelomerization data, rate constants of the interaction of 1e R-radical with ethylene [1g 1e ke=(6.1±0.2)−(21 400±1 200)/RT] and carbon tetrachloride [1g 1e kt=(7.5±0.2)−(37 000±1 200)/RT] have been calculated.

Abstract

Изучена кинетика присоединения CCl3CH2CH2Br к 1-гексуну. По найденной константе скорости присоединения CCl3CH2CH .2 - 1e R.)-радикала к 1-гексену (1g 1э Kг=(5,2±0,1)−(13 000±800)/RT), используя данные по изучению сотеломеризации этилена и 1-гексена четыреххлористым углеродом, рассчитаны константы скорости присоединения 1э R-радикала к этилену (1g 1э Kэ=(6,1±0,2)−(21 400±1200/RT) и отщепления хлора от CCl4 (1g 1э Kп=(7,5±0,2−(37 000±1 200)/RT).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ch. Walling: Free Radicals in Solution, p. 531. Inostrannaya Literatura, Moskva 1960.

    Google Scholar 

  2. A.A. Beer, P.A. Zagorets, A.G. Shostenko: Zh. Vses. Khim. obsch. Mendeleeva,18, 255 (1973)

    Google Scholar 

  3. B.A. Englin, B.N. Osipov, R.Kh. Freidlina: Izv. Akad. Nauk SSSR, Ser. Khim.,10, 2223 (1967).

    Google Scholar 

  4. V. Kim, A.G. Shostenko, L.I. Virin, E.N. Step: React. Kinet. Catal. Lett.,13, 131 (1980).

    Google Scholar 

  5. V. Kim, A.G. Shostenko, V.E. Myshkin, N.I. Kartashev: React. Kinet. Catal. Lett.,11, 241 (1979).

    Google Scholar 

  6. V. f. Inozemtsev: Thesis, p. 182, 1971.

  7. V.A. Novozhilov, A.A. Beer: Khim. Vys. Energ.,5, 79 (1971).

    Google Scholar 

  8. V.E. Myshkin: Thesis, p. 138, 1978.

  9. H.W. Melvill, J.C. Robb, R.C. Tutton: Disc. Faraday Soc.,14, 150 (1953).

    Google Scholar 

  10. Comprehensive Chemical Kinetics, Vol. 18. Selected Chemical Reactions. Ed. C. H. Bamford, C.F.H. Tipper, p. 486. New York, Amsterdam, Oxford 1976.

  11. A.G. Shostenko, V. Kim, A.V. Malkov: React. Kinet. Catal. Lett., (in press).

  12. A.G. Shostenko, V. Kim, A.V. Malkov: React. Kinet. Catal. Lett.,19, 415 (1982).

    Google Scholar 

  13. Z. Laita, Z. Machacek: J. Polym. Sci.,38, 459 (1959).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Technology, Moscow, USSR

    A. G. Shostenko, V. Kim & A. V. Malkov

Authors
  1. A. G. Shostenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Malkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shostenko, A.G., Kim, V. & Malkov, A.V. Reactivity of the CCl3CH2CH .2 radical in processes of homo-and cotelomerization of olefins with carbon tetrachloride. React Kinet Catal Lett 19, 397–400 (1982). https://doi.org/10.1007/BF02074069

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02074069

Keywords

Search

Navigation