Skip to main content
SpringerLink
Log in

Support and mixing effect of an Fe2O3 catalyst for oxidative dehydrogenation of 1-butene

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The support and mixing effects of Fe2O3 for the activity of 1-butene oxidative dehydrogenation were examined. Alumina and titania which were able to catalyze the isomerization of butene via an allyl intermediate, stimulated remarkably the formation of butadiene from butene when they were used as support or mixing component of Fe2O3 catalyst. Otherwise Fe2O3 supported on SO 2−4 ion containing Al2O3 or TiO2−Al2O3, which catalyze the isomerization via a cationic intermediate, is almost inactive for the formation of butadiene.

Abstract

Были изучены эффекты носителя и примесей на акитвность катализатора Fe2O3 в окислительном дегидрировании 1-бутена. Окиси алюминия и титана, способные катализировать изомеризацию бутена через аллильный продукт, значительно стимулировали образование бутадиена из бутена, если их использовали в качестве носителя или примеси к катализатору Fe2O3. С другой стороны, Fe2O3, нанесенный на Al2O3, содержащий ион SO −24 , или на TiO2−Al2O3, катализирующий изомеризацию через катионный промежуточный продукт, был почти полностью неактивен для образования бутадиена.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. B. Dadyburjor, S. S. Jewur, E. Ruckenstein: Catal. Rev.,19, 293 (1979).

    Google Scholar 

  2. E. Rodenas, T. Yamaguchi, H. Hattori, K. Tanabe: J. Catal.,69, 434 (1981).

    Google Scholar 

  3. M. A. Gibson, J. W. Hightower: J. Catal.,41, 420 (1976).

    Google Scholar 

  4. H. Hattori, M. Itoh, K. Tanabe: J. Catal.,41, 46 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Alcalá de Henares University, Madrid, Spain

    E. Rodenas

  2. Department of Chemistry, Faculty of Science, Hokkaido University, 060, Sapporo, Japan

    T. Iizuka & H. Katsumata

Authors
  1. E. Rodenas
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Iizuka
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Katsumata
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. Tanabe
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rodenas, E., Iizuka, T., Katsumata, H. et al. Support and mixing effect of an Fe2O3 catalyst for oxidative dehydrogenation of 1-butene. React Kinet Catal Lett 19, 341–344 (1982). https://doi.org/10.1007/BF02074058

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02074058

Keywords

Search

Navigation