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Unusual selectivity of alcohol oxidation by oxygen in aqueous alkaline solutions of copper phenanthroline complexes

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Abstract

In aqueous alkaline solutions copper phenanthroline complexes catalyze the oxidation of primary alcohols and cyclohexanol to carboxylic acids at 333–373 K and\(P_{O_2 } \)=0.2–0.4 MPa. Unlike in radical-chain and metal-complex oxidation, secondary and acyclic alcohols are not oxidized in these conditions.

Abstract

В водных щелочных растворах фенантролиновые комплексы меди катализируют окисление первичных спиртов и циклогексанола в карбоновые кислоты при температурах 333–313 К и давлении кислорода 0,2–0,4 МПа. Вторичные ациклические спирты не окисляются в этих условиях в отличие от радикальноцепного и металлокомплексного окисления.

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Authors and Affiliations

  1. Institute of Physical Organic and Coal Chemistry, Donetsk, USSR

    V. P. Tretyakov, G. P. Zimtseva, E. S. Rudakov & A. V. Bogdanov

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  1. V. P. Tretyakov
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  2. G. P. Zimtseva
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  3. E. S. Rudakov
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  4. A. V. Bogdanov
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Tretyakov, V.P., Zimtseva, G.P., Rudakov, E.S. et al. Unusual selectivity of alcohol oxidation by oxygen in aqueous alkaline solutions of copper phenanthroline complexes. React Kinet Catal Lett 19, 263–266 (1982). https://doi.org/10.1007/BF02074042

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  • DOI: https://doi.org/10.1007/BF02074042

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