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Interpretation of energy stability for Ti 7+2 and Ti 6+2 dimers

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Abstract

By using the interacting bonds method (IBM), it has been established that for the chloride Ziegler systems (TiCl4+AlR3) for polymerization the formation of Ti 7+2 and Ti 6+2 pairs is a thermodynamically favorable process.

Abstract

Для хлоридной циглеровской системы полимеризации (TiCl4+AlR3) методом взаимодействующих связей (МВС) показано, что образование пар Ti 7+2 и Ti 6+2 является заметно термодинамически выгодным.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    N. N. Bulgakov, V. F. Anufrienko & V. V. Zakharov

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  1. N. N. Bulgakov
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  2. V. F. Anufrienko
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  3. V. V. Zakharov
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Bulgakov, N.N., Anufrienko, V.F. & Zakharov, V.V. Interpretation of energy stability for Ti 7+2 and Ti 6+2 dimers. React Kinet Catal Lett 40, 221–225 (1989). https://doi.org/10.1007/BF02073797

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  • DOI: https://doi.org/10.1007/BF02073797

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