Abstract
Hydrazinium ethylenediaminetetraacetatometalate complexes of the type, N2H5 [M(Hedta)·H2O] were subjected to systematic TG/DTG analysis. The decomposition process consists of three stages. Kinetic parameters were evaluated for each of these stages using the Coats-Redfern equation.
Similar content being viewed by others
References
Pushparaja, M. Sundarsanan:Indian, J. Chem.,164, 504 (1971).
P.C. Pradhan, B.K. Mishra, G.B. Behera:Indian J. Chem., Sect. B,11, 26 (1987).
N. Saravanan, B.N. Sivasankar, S. Govindarajan, K.K. Mohammed Yusuff:Synth. React. Inorg. Met.-Org. Chem.,24, 703 (1994).
A.W. Coats, J.P. Redfern:Nature,68, 201 (1964).
R. Sreekala, K.K. Mohammed Yusuff:React. Kinet. Catal. Lett.,48, 575 (1992).
K.K. Mohammed Yusuff, R. Sreekala:Thermochim. Acta,159, 357 (1990).
K.K. Mohammed Yusuff, A.R. Karthikeyan:Thermochim. Acta,207, 193 (1992).
K.K. Mohammed Yusuff, C. Krishnakumar:React. Kinet. Catal. Lett.,49, 437 (1993).
K.K. Mohammed Yusuff, R. Sreekala:Thermochim. Acta,179, 313 (1991).
L.J. Bellamy: The infrared spectra of complex molecules, Vol. I, 3rd Edition 1975.
F.A. Cotton, Geoffrey Wilkinson: Advanced Inorganic Chemistry, 5th Edition 1988.
N.N. Greenwood, A. Earnshaw: Chemistry of the Elements, Pergamon Press Plc. 1989.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Saravanan, N., Mohammed Yusuff, K.K. Thermal decomposition kinetics of Co(II), Ni(II), Cu(II) and Zn(II) complexes of dihydrazinium ethylenediamine-tetraacetate. React Kinet Catal Lett 55, 407–414 (1995). https://doi.org/10.1007/BF02073077
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02073077