Skip to main content
Log in

Identification of mixed states using electron spectroscopy

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

X-ray photoelectron spectroscopy (XPS) is a highly surface sensitive technique and is used in identification of oxidation states in catalysts at various stages. Copper, silver and platinum based catalysts are widely used in petrochemical industries. Our attempts at characterization have revealed that elements in these catalysts are normally present then one stae. It is terefore essential to identify their in more chemical as well as oxidation states. Such identification combined with quantitative analysis of data is helpful in correlating catalyst performance. Examples of mixed state identification are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. V. DiCastro, C. Furlani, M. Margano, M. Rossi:Appl. Surf. Sci.,28, 270 (1987).

    Google Scholar 

  2. P.B. Himelfarb, F.E. Wawner, Jr., A. Bieser, Jr., S.N. Vines:J. Catal.,83, 469 (1983).

    Google Scholar 

  3. B.R. Strohmeier, D.E. Leyden, R. Scottfied, D.M. Hercules:J. Catal.,94, 514 (1985).

    Google Scholar 

  4. G.C. Shen, S.I. Fujita, N. Takezawa:J. Catal.,138, 754 (1992).

    Google Scholar 

  5. J.K. Lee, X.E. Verykois, R. Pitchai:Appl. Catal.,44, 223 (1988).

    Google Scholar 

  6. E.A. Carter, W.A. Goddard:Surf. Sci.,209, 243 (1989).

    Google Scholar 

  7. R.B. Grant, C.A.J. Harbach, R.M. Lambert, S.A. Tan:J. Chem. Soc. Faraday Trans. I,83, 2035 (1987).

    Google Scholar 

  8. C.T. Campbell, M.T. Paffett:Surf. Sci.,177, 417 (1986).

    Google Scholar 

  9. D.R. Schryer, B.T. Upchurch, J.D. Van Norman, K.G. Brown, J. Schryer:J. Catal.,122, 193 (1990).

    Google Scholar 

  10. R.F. Hicks, H. Qi, M.L. Young, R.G. Lee:J. Catal.,122, 280 (1990).

    Google Scholar 

  11. S.J. Tauster, J.J. Steger:J. Catal.,125, 387 (1990).

    Google Scholar 

  12. C.D. Wagner:J. Vac. Sci. Tech.,15, 518 (1978).

    Google Scholar 

  13. Y. Lin, I. Adler, T. Tsang, L.J. Matienzo, S.O. Grim:Chem. Phys. Lett.,24, 81 (1974).

    Google Scholar 

  14. V.K. Kaushik:Spectrochim. Acta,44B, 581 (1989).

    Google Scholar 

  15. V.K. Kaushik:J. Electron Spectr. Rel. Phenom.,56, 273 (1991).

    Google Scholar 

  16. V.K. Kaushik:Z. Phys. Chem. N.F.,173, 105 (1991).

    Google Scholar 

  17. V.K. Kaushik:Z. Phys. Chem. N.F.,168, 161 (1990).

    Google Scholar 

  18. V.K. Kaushik, M. Ravindranathan:Appl. Catal.,47, 343 (1989).

    Google Scholar 

  19. L. Petrov, A. Eliyas, D. Shopov:Appl. Catal.,24, 145 (1986).

    Google Scholar 

  20. V.K. Kaushik, M. Ravindranathan:Zeolites,12, 415 (1992).

    Google Scholar 

  21. V.K. Kaushik, Ch. Sivaraj, P. Kanta Rao:Appl. Surf. Sci.,51, 27 (1991).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

IPCL Communication No. 266

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kaushik, V.K. Identification of mixed states using electron spectroscopy. React Kinet Catal Lett 55, 355–364 (1995). https://doi.org/10.1007/BF02073071

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02073071

Keywords

Navigation