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On the kinetic interpretation of metal-support interaction

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Abstract

Metal-support interaction (MSI) in catalysis is discussed in terms of the surface electron gas model (SEGM), which accounts for the case of inhomogenous surface. In the case of MSI the initial heat of adsorption as well as the effective charge of adsorbed particles can differ from that in the absence of metal-support interaction. Conditions at which either negligible small adsorption coefficients (reaction rate) or their enhancement compared to non-MSI conditions are presented.

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Author notes

  1. Dmitry Murzin

    Present address: Department of Chemical Kinetics and Catalysis, Karpov Institute of Physical Chemistry, Obukha 10, 103064, Moscow, Russia

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  1. Laboratory of Industrial Chemistry, Åbo Akademi, Biskopsgatan 8, FIN-20500, Åbo, Finland

    Dmitry Murzin

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Murzin, D. On the kinetic interpretation of metal-support interaction. React Kinet Catal Lett 55, 275–281 (1995). https://doi.org/10.1007/BF02073061

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  • DOI: https://doi.org/10.1007/BF02073061

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