Reaction Kinetics and Catalysis Letters

, Volume 55, Issue 2, pp 245–250 | Cite as

Dehydrogenation of methanol to methyl formate over supported Ni, Pd and Pt catalysts. Anomalous catalytic functions of PdZn and PtZn alloys

  • N. Iwasa
  • T. Akazawa
  • S. Ohyama
  • K. Fujikawa
  • N. Takezawa
Article

Abstract

Pd/ZnO and Pt/ZnO exhibited high catalytic performance for the dehydrogenation of methanol to methyl formate upon the formation of PdZn and PtZn alloys.

Keywords

Methyl Methanol Physical Chemistry Catalysis Dehydrogenation 

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References

  1. 1.
    G.C. Bond:Catalysis by Metals. Academic Press, New York 1964.Google Scholar
  2. 2.
    I. Yasumori, E. Miyazaki:J. Chem. Soc. Japan (in Japanese),92, 659 (1971).Google Scholar
  3. 3.
    N. Iwasa, O. Yamamoto, T. Akazawa, S. Ohyama, N. Takezawa:J. Chem. Soc., Chem. Comm., 1322 (1991).Google Scholar
  4. 4.
    P.S. Wehner, B.L. Gustafson:J. Catal.,88, 246 (1984).Google Scholar
  5. 5.
    A. Sárkány, Z. Zsoldos, F. Furlong, J.W. Hightower, L. Guczi:J. Chtal.,141, 566 (1993).Google Scholar
  6. 6.
    N. Iwasa, S. Kudo, H. Takahashi, S. Masuda, N. Takezawa:Catal Lett.,19, 211 (1993).Google Scholar
  7. 7.
    J.E. Benson, H.S. Hwang, M. Boudart:J. Catal.,30, 146 (1973).Google Scholar
  8. 8.
    ASM 6-620.Google Scholar
  9. 9.
    ASTM 6-0604.Google Scholar

Copyright information

© Akadémiai Kiadó 1995

Authors and Affiliations

  • N. Iwasa
    • 1
  • T. Akazawa
    • 1
  • S. Ohyama
    • 1
  • K. Fujikawa
    • 1
  • N. Takezawa
    • 1
  1. 1.Division of Materials Science and Engineeering, Faculty of EngineeringHokkaido UniversitySapporoJapan

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