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A comparative FT-IR spectroscopic study of methanethiol and methanol adsorption on sodium X and Y zeolites

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Abstract

Adsorption of CH3SH and CH3OH on activated NaX and NaY zeolites has been studied by IR spectroscopy. Only NaX is able to provoke the dissociative adsorption of CH3SH at room temperature and that of CH3OH at 623 K. Results are discussed taking into account sodium cations in the SIII position.

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Authors and Affiliations

  1. Faculty of Chemistry, A. Mickiewicz University, 60-780, Poznan, Poland

    M. Ziolek & J. Czyzniewska

  2. Laboratoire Catalyse et Spectrochimie-URA CNRS 0414, ISMRA-UNIVERSITÉ-6, Boulevard du Maréchal Juin, 14050, Caen Cedex, France

    J. Lamotte & J. C. Lavalley

Authors
  1. M. Ziolek
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  2. J. Czyzniewska
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  3. J. Lamotte
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  4. J. C. Lavalley
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Ziolek, M., Czyzniewska, J., Lamotte, J. et al. A comparative FT-IR spectroscopic study of methanethiol and methanol adsorption on sodium X and Y zeolites. React Kinet Catal Lett 53, 339–346 (1994). https://doi.org/10.1007/BF02073040

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  • DOI: https://doi.org/10.1007/BF02073040

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