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Stibene epoxidation with t-butyl hydroperoxide and hydrogen peroxide catalyzed by transition metal substituted heteropolytungstates

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Abstract

Tetra-n-butylammonium salts of transition metal-substituted heteropolytungstates, PW11MO n−39 , catalyze the epoxidation of stilbenes by t-butyl hydroperoxide (M=CoII, MnII, CuII, TiIV, RuIV, VV, NbV) and hydrogen peroxide (M=ZrIV) in acetonitrile. Epoxidation of cis-stilbene is non-stereospecific.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    O. A. Kholdeeva, G. M. Maksimov, M. A. Fedotov & V. A. Grigoriev

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  1. O. A. Kholdeeva
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  2. G. M. Maksimov
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  3. M. A. Fedotov
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  4. V. A. Grigoriev
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Kholdeeva, O.A., Maksimov, G.M., Fedotov, M.A. et al. Stibene epoxidation with t-butyl hydroperoxide and hydrogen peroxide catalyzed by transition metal substituted heteropolytungstates. React Kinet Catal Lett 53, 331–337 (1994). https://doi.org/10.1007/BF02073039

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  • DOI: https://doi.org/10.1007/BF02073039

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