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A comparative study of [Co(NH3)5ONO]XY↔[Co(NH3)5NO2]XY (XY=Cl2, Br2, I2, (NO3)2 Cl; NO3) solid-state isomerization kinetics

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Abstract

Quantitative IR investigation of solid-state [Co(NH3)5ONO]XY↔[Co(NH3)5NO2]XY (XY=Cl2, Br2, I2, (NO3)2′ Cl; NO3) linkage isomerization in KBr pellets has shown the kinetics to depend upon the outer-sphere anion. The red shift of the υ5(ONO) band during isomerization is a linear function of transformation degree.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Siberian Branch of RAS, 630091, Novosibirsk, Russian

    V. E. Dulepov & E. V. Boldyreva

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    E. V. Boldyreva

Authors
  1. V. E. Dulepov
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  2. E. V. Boldyreva
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Dulepov, V.E., Boldyreva, E.V. A comparative study of [Co(NH3)5ONO]XY↔[Co(NH3)5NO2]XY (XY=Cl2, Br2, I2, (NO3)2 Cl; NO3) solid-state isomerization kinetics. React Kinet Catal Lett 53, 289–296 (1994). https://doi.org/10.1007/BF02073033

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  • DOI: https://doi.org/10.1007/BF02073033

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