Abstract
Low temperature oxygen chemisorption (LTOC) has been applied to characterize a series of TiO2 and ZrO2 supported Mo-oxide catalysts. The monolayer coverage of the surface is completed when the Mo loading reaches 6% and 4% on the TiO2 and ZrO2 supports, respectively. The results are explained with the help of a “Patch” model of the Mo-oxide phase.
Abstract
Низкотемпературная хемосорбция кислорода использовалась для характеристики серии Mo-окисных катализаторов на TiO2 и ZrO2 носителях. Монослойное покрытие поверхности завершается когда содержание Mo на TiO2 и ZrO2 носителях достигает 6% и 4%, соответственно. Результаты объясняют на основе модели “Patch” Mo-окисной фазы.
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References
F.E. Massoth: Adv. Catal.,27, 265 (1978).
B.S. Parekh, S.W. Weller: J. Catal.,47, 100 (1977).
W.K. Hall: Proc. Forth Climax Molybdenum Conf. on the Chemistry and Uses of Molybdenum (H.F. Barry and P.C.H. Mitchell, Eds.), p. 224 Michigan, USA, 1982.
B. Mahipal Reddy, K.V.R. Chary, N.K. Nag, G. Muralidhar, V.S. Subrahmanyam: Proc. First Indo-Soviet Seminar on Catalysis, Novosibirsk, USSR, p. 47 (1984).
B. Mahipal Reddy, K.V.R. Chary, V.S. Subrahmanyam, N.K. Nag: J. Chem. Soc., Faraday Trans I (in press).
N.K. Nag, K.V.R. Chary, B. Mahipal Reddy, B. Rama Rao, V.S., Subrahmanyam: Appl. Catal.,9, 225 (1984).
S.W. Weller: Acc. Chem. Res.,16, 101 (1983).
N.K. Nag: J. Catal.,92, 432 (1985).
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Reddy, B.M., Subrahmanyam, V.S. Characterization of titania and zirconia supported molybdenum oxide catalysts by low temperature oxygen chemisorption. React Kinet Catal Lett 31, 429–433 (1986). https://doi.org/10.1007/BF02072983
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DOI: https://doi.org/10.1007/BF02072983