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Reaction Kinetics and Catalysis Letters

, Volume 12, Issue 2, pp 131–137 | Cite as

On the pattern of hydrogenolysis of hexane isomers over four Group VIIIB metals

  • Z. Paál
  • P. Tétényi
Article

Abstract

The hydrogenolysis patterns of five hexane isomers have been compared over Rh, Pd, Ir and Pt. The selectivity of rupture of various C−C bond types is different for various metals. The “fingerprint-like” patterns are, as a rule, similar to those reported in the literature, their correlation with the position of the metal in the periodic system is pointed out.

Keywords

Physical Chemistry Hexane Catalysis Periodic System Bond Type 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Изучен характеристический гидрогенолиз 5-и изомерных гексанов на катализаторах Rh, Pd, Ir и Pt. Селективность разрыва отдельных типов C−C связей отличается для различных металлов Характеристики, рассматриваемые как “отпечатки пальца” подобны к литературным данным. Отмечается их корреляция с положением данного металла в периодической системе.

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Copyright information

© Akadémiai Kiadó 1979

Authors and Affiliations

  • Z. Paál
    • 1
  • P. Tétényi
    • 1
  1. 1.Institute of Isotopes of the Hungarian Academy of SciencesBudapestHungary

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