Reaction Kinetics and Catalysis Letters

, Volume 12, Issue 1, pp 95–99 | Cite as

Catalytic properties of nickel phosphates. Isomerization of butenes

  • M. Tyblewski
  • St. Malinowski


The effect of calcination temperature on the catalytic properties of nickel phosphate has been studied using the isomerization of butene-1 as a test reaction. A simple relationship was found between the catalyst activity in isomerization and the hydroxy content of the catalyst surface. Interrelations between the activity of the catalyst and its structure are discussed.


Phosphate Physical Chemistry Nickel Catalysis Catalyst Activity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Зффект температуры кальцинирования на каталитические свойства фосфата никеля были изучены, используя изомеризацию бутена-1 в качестве модельной реакции. Простая зависимость существует между катлитической активностью в изомеризации и содержанием гидроксила на поверхности катализатора. Обсуждаются зависимость активности катализатора от его структуры.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    M. Sato, T. Konbayashi, et al.: J. Catal.,7, 342 (1967).Google Scholar
  2. 2.
    W. O. Haag, H. Pines: J. Amer. Chem. Soc.,82, 387 (1960).Google Scholar
  3. 3.
    M. J. Baird, J. H. Lunsford: J. Catal.,26, 440 (1972).Google Scholar
  4. 4.
    J. Turkevich, R. V. Smith: J. Chem. Phys.,16, 466 (1948).Google Scholar
  5. 5.
    S. Malinowski, M. Tyblewski: J. Colloid Interface Sci., (to be published).Google Scholar

Copyright information

© Akadémiai Kiadó 1979

Authors and Affiliations

  • M. Tyblewski
    • 1
  • St. Malinowski
    • 1
  1. 1.Institute of Organic Chemistry and TechnologyWarsaw Technical UniversityWarszawaPoland

Personalised recommendations