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Studies on the extraction behavior of Zr(IV), Ce(III), Th(IV) and U(VI) from aqueous solutions of Arsenazo-I with HDEHP, HTTA, TDA and TCMA

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Abstract

The extraction behavior of Zr(IV), Ce(III), Th(IV) and U(VI) from aqueous solutions containing Arsenazo-I with the organic solvents tridodecylamine (TDA), 1-[thenoyl-(2)]-3-3-3-trifluoroacetone (HTTA), di(2-ethylhexyl) phosphoric acid (HDEHP) and tricaprylmethylammonium chloride (TCMA) in xylene has been investigated. Effect of hydrogen ion concentration in the aqueous phase, Arsenazo-I concentration, as well as the effect of solvent concentration on the extraction was studied. Some alternatives for separation of the elements studied were recommended enabling the spectrophotometric determination of these elements using Arsenazo-I without interference.

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References

  1. Z. MARCZENKO, Separation and Spectrophotometric Determination of Elements, Horwood, Chichester, 1986.

    Google Scholar 

  2. V. I. KUZNETSOV, S. B. SAVVIN, Mitteilungsblatt Chem. Gesellschaft, Anal. Chem. Sond., 161 (1960).

  3. E. CERRAI, G. GHERSINI, Anal. Chim. Acta, 37 (1967) 295.

    Google Scholar 

  4. V. I. KUZNETSOV, S. B. SAVVIN, Radiokhimiya, 2 (1960) 682.

    Google Scholar 

  5. V. I. KUZNETSOV, S. B. SAVVIN, Dokl. Akad. Nauk. SSSR, 140 (1961) 125.

    Google Scholar 

  6. A. A. NEMODRUK, L. P. GLUKHOVA, Zh. Analit. Khim., 23 (1968) 552.

    Google Scholar 

  7. R. LEVIN, S. RONEN, Report NRCN-433.

  8. R. RASTOGI, H. R. MHATRE, M. A. MAHAJAN, N. K. CHAUDHURI, S. K. PATIL, Mikrochim. Acta, 1 (1991) 45.

    Google Scholar 

  9. M. A. SAWANT, S. M. KHOPKAR, Indian J. Chem., 21 (1982) No. 6, 658.

    Google Scholar 

  10. P. K. S. KARTHA, J. A. KASI, A. RAMANUJAM, M. N. NADKARNI, Bhabha Atomic Research Centre, Bombay (India) Report, BARC-1190, 1983.

  11. K. SEKINE, Z. Anal. Chem., 288 (1977) 47.

    Google Scholar 

  12. R. KEIL, Z. Anal. Chem., 286 (1977) 54.

    Google Scholar 

  13. K. SEKINE, Microchim. Acta, 5 (1976) 559.

    Google Scholar 

  14. M. R. SHIVADE, V. M. SHINDE, Fresen. Z. Anal. Chem., 317 (1984) 792.

    Google Scholar 

  15. T. ISHIMORI, E. NAKAMURA, JAERI Report, 1963, p. 1047.

  16. K. BURGER, Organic Reagents in Metal Analysis, Akadémiai Kiadó, Budapest, 1973.

    Google Scholar 

  17. H. KHALIFA, Y. M. ISSA, Egypt J. Chem., 17 (1974) 581.

    Google Scholar 

  18. S. B. SAVVIN, E. L. KUZIN, Zh. Analit. Khim., 22 (1967) 105.

    Google Scholar 

  19. C. F. COLEMAN, Atomic Energy Rew. IAEA, 2 (1964) 2, 3.

    Google Scholar 

  20. G. KOCH, Report KfK-377, Aug. 1965.

  21. S. B. SAVVIN, Talanta, 11 (1964) 7.

    Google Scholar 

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Authors and Affiliations

  1. Nuclear Chemistry Department, Hot Laboratories Centre, Atomic Energy Authority, Post Code 13759, Cairo, (Egypt)

    F. H. El-Sweify & M. M. Kamel

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  1. F. H. El-Sweify
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  2. M. M. Kamel
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El-Sweify, F.H., Kamel, M.M. Studies on the extraction behavior of Zr(IV), Ce(III), Th(IV) and U(VI) from aqueous solutions of Arsenazo-I with HDEHP, HTTA, TDA and TCMA. Journal of Radioanalytical and Nuclear Chemistry, Articles 207, 369–382 (1996). https://doi.org/10.1007/BF02071242

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