Abstract
The catalytic activity of transition metal silicides in H2 oxidation is much higher compared to metal-like carbides, which can be due to the lower electronegativity of silicon compared to carbon.
Abstract
Силициды переходных металлов проявляют высокую каталитическую активность в реакции окисления водорода, превосходящую активность металлоподобных карбидов, что объясняется меньшей электроотрицательностью кремния по сравнению с углеродом.
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Vlasenko, N.V., Ilchenko, N.I. Catalytic activity of transition metal silicides in hydrogen oxidation. React Kinet Catal Lett 36, 189–193 (1988). https://doi.org/10.1007/BF02071162
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DOI: https://doi.org/10.1007/BF02071162