Abstract
A complex approach to the development of kinetic models in terms of the joint kinetic and physicochemical methods is suggested. To establish kinetic models for the hydrogenation of C5, C15 and C20 acetylene alcohols on a modified Pd/Al2O3 (0.5% Pd) catalyst, the kinetics of their selective hydrogenation and the adsorption of their components have been studied.
Abstract
Предложен комплексный подход к овоснованию кинетических моделей на основе кинетических и физико-химических методов. Для установления кинетических моделей гидрирования ацетиленовых спиртов C5, C15, C20 на модифицированном Pd/Al2O3 (0,5% Pd), выла изучена кинетика их селективного гидрирования и характер адсорвции компонентов.
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Sulman, E.M., Popov, O.S., Yermakova, A. et al. Kinetic model and mechanism for selective hydrogenation of acetylene alcohols. React Kinet Catal Lett 36, 59–64 (1988). https://doi.org/10.1007/BF02071141
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DOI: https://doi.org/10.1007/BF02071141