Abstract
This paper reports on the synthesis and characterization of various mixed orthophosphates [NaMgPO4, Na4Mg(PO4)2 and NaMg4(PO4)3] obtained from freshly prepared Mg3(PO4)2 gel by using various treatments. The solids exhibit excellent selectivity in the gas-phase conversion of cyclohexanol (CHOL) to cyclohexanone (CHONE).
Similar content being viewed by others
References
C. Fernández, J. Grosmangin, G. Czabo, J. C. Vedrine:Appl. Catal.,27, 353 (1986).
M.A. Aramendía, J. Barrios, V. Borau, C. Jiménez, J.M. Marinas, F.J. Romero, J. R. Ruiz, F.J. Urbano:Stud. Surf. Sci. Catal.,82, 769 (1994).
J.M. Campelo, A. García D. Luna, J.M. Marinas, M.S. Moreno:J. Chem. Soc. Faraday Trans. I,85, 2535 (1989).
K. Tanabe, M. Misono, Y. Ono, H. Hattori:Stud. Surf. Sci. Catal.,51 (1989).
F. Figueras-Rocca, L. Mourgues, Y. Trambouze:J. Catal.,14, 107 (1969).
K. Tomke:Z. Phys. Chem. NF,106, 225 (1977).
Y. Matsumura, K. Hashimoto, S. Yoshida:J. Catal.,117, 135 (1989).
V. Perrichon, M. C. Durupty:Appl. Catal.,42, 217 (1988).
K. Ganesan, C.N. Pillai:J. Catal.,119, 8 (1989).
X. Montagne, C. Durand, G. Mabilon:Stud. Surf. Sci. Catal. 20, 33 (1985).
M.A. Aramendía, V. Borau, C. Jiménez, J.M. Marinas, F. J. Romero:J. Catal.,151, 44 (1995).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Aramendía, M.A., Borau, V., Jiménez, C. et al. Synthesis and catalytic activity of sodium-magnesium orthophosphates of different stoichiometry. React Kinet Catal Lett 58, 183–191 (1996). https://doi.org/10.1007/BF02071123
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02071123