Abstract
The kinetic coupling in the case of complex coupled catalytic reactions leads to substantial changes in selectivity. The consecutive catalytic reaction mechanism of type A(+B)→C(+B)→D is considered and it is demonstrated that the selectivity pattern is determined by the pressure of B.
Similar content being viewed by others
References
J. Horiuti, T. Nakamura:Z. Phys. Chem.,11, 358 (1957).
M. Temkin:Adv. Catal.,28, 173 (1979).
J. Horiuti:Ann. N.Y. Acad. Sci.,213, 5 (1973).
M. Temkin:Dokl. AN SSSR.,152, 156 (1963).
M. Temkin:Int. Chem. Eng.,11, 709 (1971).
J. Happel, P.H. Sellers:Adv. Catal.,32, 274 (1983).
Yu.S. Snagovskii, G.M. Ostrovskii:Kinetic Modeling of Heterogeneous Catalytic Reactions (in Russian), Khimiya, Moskva 1976.
A.G. Zyskin, Yu.S. Snagovskii, G.M. Ostrovskii:Kinet. Katal.,18, 212 (1977).
G.M. Ostrovskii, A.G. Zyskin, Yu.S. Snagovskii:Comput. Chem.,11, 85 (1987).
J.A. Dumesic, D. Rudd, L.M. Aparicio, J.E. Rekoske, A.A. Treviño:The Mikrokinetics of Heterogeneous Catalysis, Am. Chem. Soc., Washington, D.C. 1993.
M. Boudart:Ind. Eng. Chem. Res.,33, 2900 (1994).
M. Boudart, G. Djéga-Mariadassou:Catal. Lett.,29, 7 (1994).
J. Halpern:Pure Appl. Chem.,18, 59 (1978).
S.L. Kiperman:Int. Chem. Eng.,18, 59 (1978).
S.L. Kiperman:Kinet. Katal.,22, 30 (1981).
D.Yu. Murzin, N.V. Kul'kova, M.I. Temkin:Kinet. Katal.,31, 983 (1990).
Z.T. Beisembaeva, B.S. Gudkov, M.S. Kharson, N.I. Popov, S.L. Kiperman:Izv. AN SSSR, Ser. Khim., 12 (1974).
C. Niklasson, B. Andersson, N.-H. Schöön:Ind. Eng. Chem. Res.,26, 1459 (1987).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Murzin, D.Y. Kinetic coupling and selectivity pattern in consecutive heterogeneous catalytic reactions. React Kinet Catal Lett 58, 65–72 (1996). https://doi.org/10.1007/BF02071106
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02071106