Skip to main content
Log in

Kinetic coupling and selectivity pattern in consecutive heterogeneous catalytic reactions

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The kinetic coupling in the case of complex coupled catalytic reactions leads to substantial changes in selectivity. The consecutive catalytic reaction mechanism of type A(+B)→C(+B)→D is considered and it is demonstrated that the selectivity pattern is determined by the pressure of B.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Horiuti, T. Nakamura:Z. Phys. Chem.,11, 358 (1957).

    Google Scholar 

  2. M. Temkin:Adv. Catal.,28, 173 (1979).

    Google Scholar 

  3. J. Horiuti:Ann. N.Y. Acad. Sci.,213, 5 (1973).

    PubMed  Google Scholar 

  4. M. Temkin:Dokl. AN SSSR.,152, 156 (1963).

    Google Scholar 

  5. M. Temkin:Int. Chem. Eng.,11, 709 (1971).

    Google Scholar 

  6. J. Happel, P.H. Sellers:Adv. Catal.,32, 274 (1983).

    Google Scholar 

  7. Yu.S. Snagovskii, G.M. Ostrovskii:Kinetic Modeling of Heterogeneous Catalytic Reactions (in Russian), Khimiya, Moskva 1976.

    Google Scholar 

  8. A.G. Zyskin, Yu.S. Snagovskii, G.M. Ostrovskii:Kinet. Katal.,18, 212 (1977).

    Google Scholar 

  9. G.M. Ostrovskii, A.G. Zyskin, Yu.S. Snagovskii:Comput. Chem.,11, 85 (1987).

    Google Scholar 

  10. J.A. Dumesic, D. Rudd, L.M. Aparicio, J.E. Rekoske, A.A. Treviño:The Mikrokinetics of Heterogeneous Catalysis, Am. Chem. Soc., Washington, D.C. 1993.

    Google Scholar 

  11. M. Boudart:Ind. Eng. Chem. Res.,33, 2900 (1994).

    Google Scholar 

  12. M. Boudart, G. Djéga-Mariadassou:Catal. Lett.,29, 7 (1994).

    Google Scholar 

  13. J. Halpern:Pure Appl. Chem.,18, 59 (1978).

    Google Scholar 

  14. S.L. Kiperman:Int. Chem. Eng.,18, 59 (1978).

    Google Scholar 

  15. S.L. Kiperman:Kinet. Katal.,22, 30 (1981).

    Google Scholar 

  16. D.Yu. Murzin, N.V. Kul'kova, M.I. Temkin:Kinet. Katal.,31, 983 (1990).

    Google Scholar 

  17. Z.T. Beisembaeva, B.S. Gudkov, M.S. Kharson, N.I. Popov, S.L. Kiperman:Izv. AN SSSR, Ser. Khim., 12 (1974).

  18. C. Niklasson, B. Andersson, N.-H. Schöön:Ind. Eng. Chem. Res.,26, 1459 (1987).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Murzin, D.Y. Kinetic coupling and selectivity pattern in consecutive heterogeneous catalytic reactions. React Kinet Catal Lett 58, 65–72 (1996). https://doi.org/10.1007/BF02071106

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02071106

Keywords

Navigation