Skip to main content
Log in

Sodium removal and catalytic properties of HNaZSM-20 zeolite. Comparison with Y zeolite

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

A series of HNaZSM-20 catalysts with a varying amount of sodium cations were studied. The samples were prepared by ion exchange starting with a NaZSM-20 sample. The observedammonium-sodium exchange efficiency was slightly higher for ZSM-20 than for Y zeolite. The HNaZSM-20 series presentedhigher cracking activities in then-heptane transformation than the corresponding HNaY series. A decrease in theselectivity for coke deposition with sodium removal was also observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Ciric (Mobil Oil Corporation): U.S. 3,972,983 (1976).

  2. E.G. Derouane, N. Dewaele, Z. Gabelica, J.B. Nagy:Appl. Catal.,28, 285 (1986).

    Google Scholar 

  3. S. Ernst, G.T. Kokotailo, J. Weitkamp:Zeolites,7, 180 (1987).

    Google Scholar 

  4. J.M. Newsam, M.M.J. Treacy, D.E.W. Vaughan, K.G. Strohmaier, W.J. Mortier:J. Chem. Soc., Chem. Commun.,8, 493 (1989).

    Google Scholar 

  5. D.E.W. Vaughan, M.M.J. Treacy, J.M. Newsam, K.G. Strohmaier, W.J. Mortier:ACS Symp. Ser.,398, 544 (1989).

    Google Scholar 

  6. J. Dwyer, D. Millward, P.J. O'Malley, A. Araya, A. Corma, V. Fornes, A. Martinez:J. Chem. Soc. Faraday Trans. I,86, 1001 (1990).

    Google Scholar 

  7. J.M. Lopes, F. Lemos, F.R. Ribeiro, N. Dewaele, E.G. Derouane, M. Guisnet:J. Mol. Catal.,48, 373 (1988).

    Google Scholar 

  8. F. Lemos, J.M. Lopes, F. Ramôa Ribeiro, E.G. Derouane:Appl. Catal.,49, 175 (1989).

    Google Scholar 

  9. N. Dewaele, L. Maistriau, J.B. Nagy, Z. Gabelica, E.G. Derouane:Appl. Catal.,37, 273 (1988).

    Google Scholar 

  10. F. Lemos: Ph.D. Thesis, Instituto Superior Técnico, Lisboa, 1989.

  11. V. Fülöp, G. Borbély, H.K. Beyer, S. Ernst, J. Weitkamp:J. Chem. Soc., Faraday Trans. I,85, 2127 (1989).

    Google Scholar 

  12. J.M. Lopes, F. Lemos, F. Ramôa Ribeiro, E.G. Derouane, P. Magnoux, M. Guisnet:Appl. Catal. A,114, 161 (1994).

    Google Scholar 

  13. I.V. Mishin, A.V. Kliachko, T.R. Brueva, V.D. Nissenbaum, H.G. Karge:Kinet. Katal.,34, 835 (1993).

    Google Scholar 

  14. R. Kumar, W-C. Cheng, K. Rajagopalan, A.W. Peters, P. Basu:J. Catal.,143, 594 (1993).

    Google Scholar 

  15. W.J. Wojciechowski, A. Corma:Catalytic Cracking, Marcel Dekker, New York 1986.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lopes, J.M., Lemos, F., Derouane, E. et al. Sodium removal and catalytic properties of HNaZSM-20 zeolite. Comparison with Y zeolite. React Kinet Catal Lett 58, 33–38 (1996). https://doi.org/10.1007/BF02071102

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02071102

Keywords

Navigation