Reaction Kinetics and Catalysis Letters

, Volume 46, Issue 2, pp 359–364 | Cite as

Homogeneous catalytic oligomerization of terminal alkynes and metathesis of internal alkynes using group VIB metal carbonyl based complexes

  • C. P. Tsonis
Article

Abstract

Terminal alkynes oligomerize in the presence of group VIB metal carbonyl catalysts when they are thermally activated, but internal ones undergo metathesis instead.

Keywords

Physical Chemistry Catalysis Carbonyl Oligomerization Alkyne 

Abstract

В то время как конечные алкины олигомеризуются в присутствии катализаторов карбонилов металлов группы VIB во время их термическои активации, внутренние алкины, вместо этого, подвергаются метатезису.

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Copyright information

© Akadémiai Kiadó 1992

Authors and Affiliations

  • C. P. Tsonis
    • 1
  1. 1.Department of ChemistryKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia

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