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Mechanism of alkylation in the dehydrocyclization of hexane on metals

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Abstract

The formation of toluene on nickel was investigated by a tracer technique. It was established that the hydrogenolysis of benzene is faster than its formation and this yields monocarbon fragments which are available for alkylation. On platinum toluene is not formed owing to the lack of benzene decomposition.

Abstract

Образование толуола на никеле было исследовано с помощью изотопной техники. Было обнаружено, что гидрогенолиз бензола протекает быстрее, чем его образование, что ведет к образованию моноуглеродных фрагментов, способных принимать участие в алкилировании. На платине толуол не образуется, вследствие отсутствия разложения бензола.

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References

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Authors and Affiliations

  1. Institute of Isotopes, Hungarian Academy of Sciences, Budapest, Hungary

    L. Guczi, K. Matusek & P. Tétényi

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  1. L. Guczi
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  2. K. Matusek
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  3. P. Tétényi
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Guczi, L., Matusek, K. & Tétényi, P. Mechanism of alkylation in the dehydrocyclization of hexane on metals. React Kinet Catal Lett 1, 291–295 (1974). https://doi.org/10.1007/BF02070896

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  • DOI: https://doi.org/10.1007/BF02070896

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