Abstract
In a single-step synthesis, terminal N-monomethyl-N-alkylamines and N, N-dimethyl-N-alkylamines were obtained from carbon monoxide, steam and monomethylamine or dimethylamine, respectively. The reaction mechanism is similar to that suggested by Kölbel and Trapper/1, 2/for the synthesis of primary amines.
Abstract
с помошью одноступенчатого синтеза были получены Н-монометил-Н-алкиламины и Н,Н-диметил-Н-алкиламины из окиси углерода, водяного пара, монометиламина и диметиламина, соответственно. Механизм реакции подобен механизму синтеза первичных аминов, предложенного Кёльбелем и Траппером.
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References
H. Kölbel, J. Trapper: Angew, Chemie, Int. Ed.,5, 843 (1966)
H. Kölbel, H. Hammer, J. Trapper: Brennstoff-Chemie,45, 214 (1964)
H. Kölbel: Chemische Technologie, Vol. 3, p. 439 K. Winnacker and L. Küchler, München 1959
H. Kölbel, G. Patzschke, H. Hammer: Brennstoff-Chemie, 47, 4 (1966)
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Kölbel, H., Abdulahad, I., Kanowski, S. et al. Formation of terminal secondary and tertiary alkylamines by single-step synthesis from carbon monoxide, steam and monomethylamine and dimethylamine, respectively. React Kinet Catal Lett 1, 267–270 (1974). https://doi.org/10.1007/BF02070892
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DOI: https://doi.org/10.1007/BF02070892