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Reaction Kinetics and Catalysis Letters

, Volume 21, Issue 3, pp 357–360 | Cite as

Kinetics and selectivity of the oxidation of alkanes in Cl2−H2O and Cl2−Hg2+−H2O solutions

  • E. S. Rudakov
  • L. K. Volkova
  • V. P. Tretiakov
Article

Abstract

Relative oxidation rate constants of several normal, iso-, cyclo-and methylcycloalkanes have been measured in Cl2−H2O and Cl2−Hg2+−H2O solutions at 343K. The selectivity of C−H bond dissociation in both systems is the same. HOCl is assumed to be the active species for the two systems.

Keywords

Oxidation Physical Chemistry Catalysis Alkane Oxidation Rate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

В растворах Cl2−H2O и Cl2−Hg2+−H2O при 343 К измерены относительные константы скорости окисления ряда нормальных, изо-,цикло-и метилциклоалканов; селективность расщелления C−H связи в обеих системах одинакова. Заключено, что активной частицей в обеих системах является кислота HOCl.

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Copyright information

© Akadémiai Kiadó 1982

Authors and Affiliations

  • E. S. Rudakov
    • 1
  • L. K. Volkova
    • 1
  • V. P. Tretiakov
    • 1
  1. 1.Institute of Physical Organic and Carbon ChemistryDonetskUSSR

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