Reaction Kinetics and Catalysis Letters

, Volume 21, Issue 3, pp 357–360 | Cite as

Kinetics and selectivity of the oxidation of alkanes in Cl2−H2O and Cl2−Hg2+−H2O solutions

  • E. S. Rudakov
  • L. K. Volkova
  • V. P. Tretiakov


Relative oxidation rate constants of several normal, iso-, cyclo-and methylcycloalkanes have been measured in Cl2−H2O and Cl2−Hg2+−H2O solutions at 343K. The selectivity of C−H bond dissociation in both systems is the same. HOCl is assumed to be the active species for the two systems.


Oxidation Physical Chemistry Catalysis Alkane Oxidation Rate 
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В растворах Cl2−H2O и Cl2−Hg2+−H2O при 343 К измерены относительные константы скорости окисления ряда нормальных, изо-,цикло-и метилциклоалканов; селективность расщелления C−H связи в обеих системах одинакова. Заключено, что активной частицей в обеих системах является кислота HOCl.


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Copyright information

© Akadémiai Kiadó 1982

Authors and Affiliations

  • E. S. Rudakov
    • 1
  • L. K. Volkova
    • 1
  • V. P. Tretiakov
    • 1
  1. 1.Institute of Physical Organic and Carbon ChemistryDonetskUSSR

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