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Comparative study of the activity of Al−Pd and Al−Pt catalysts in deep oxidation of hydrocarbons

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Abstract

Atomic catalytic activity of palladium has been revealed to be higher than that of platinum in deep oxidation of methane and lower in the case of butane. According to the experimental data and the quantum-chemical calculation, the observed effects are ascribed to the different bond strength of the surface oxygen due to different reaction conditions.

Abstract

Найдено, что в реакции глубокого окисления метана АКАPd выше АКАPt, в. то время как в реакции глубокого окисления бутана АКАPd выше АКАPt На основании эксперименталвных данных и квантово-химического расчёта предложено объяснение наблюдаемых эффектов, связанных с различной прочностью связи поверхностного кислорода в зависимости от условий проведения реакций.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    V. A. Drozdov, P. G. Tsyrulnikov, V. V. Popovskii, N. N. Bulgakov, E. M. Moroz & T. G. Galeev

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  1. V. A. Drozdov
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  2. P. G. Tsyrulnikov
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  3. V. V. Popovskii
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  4. N. N. Bulgakov
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  5. E. M. Moroz
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  6. T. G. Galeev
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Drozdov, V.A., Tsyrulnikov, P.G., Popovskii, V.V. et al. Comparative study of the activity of Al−Pd and Al−Pt catalysts in deep oxidation of hydrocarbons. React Kinet Catal Lett 27, 425–427 (1985). https://doi.org/10.1007/BF02070487

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  • DOI: https://doi.org/10.1007/BF02070487

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