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Catalytic properties of some copper intermetallides in the oxidative dehydrogenation of methanol

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Abstract

Catalytic properties of copper intermetallides with Mg, Ga, In, La, Pr, Si, Ti, Ge, Zr, Sn, Se and Te have been examined. Most selective with respect to the yield of formaldehyde are Cu3Si and Cu31Sn8. Cu9Ga4, Cu3Ge, Cu2Se and Cu2Te are catalytically inactive. Cu6La and Cu6Pr possess high dehydrogenating activity but are not selective toward formaldehyde.

Abstract

Исследованы каталитические свойства интерметаллидов меди с Mg, Ga, In, La, Pr, Si, Ge, Zr, Sn, Se, Te. Наиболее избирательны в отношении выхода формальдегида Cu3Si и Cu31Sn8. Cu9Ga4, Cu3Ge, Cu2Se и Cu2Te каталитически не активны. Cu6La и Cu6Pr облададают сильной дегидрирующей способностью, но не избирательны в отношении выхода формальдегида.

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References

  1. V. S. Kovalenko: Metallographic Reactants, Metallurgia, Moskva 1970.

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  2. B. I. Popov, N. G. Skomorokhova: React. Kinet. Catal. Lett.,25, (1984) (in press).

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    B. I. Papov & N. G. Skomorokhova

  2. GIPROTzvetmetobrabotka, Moscow, USSR

    V. V. Karonik & V. E. Kolesnichenko

Authors
  1. B. I. Papov
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  2. N. G. Skomorokhova
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  3. V. V. Karonik
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  4. V. E. Kolesnichenko
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Papov, B.I., Skomorokhova, N.G., Karonik, V.V. et al. Catalytic properties of some copper intermetallides in the oxidative dehydrogenation of methanol. React Kinet Catal Lett 27, 419–423 (1985). https://doi.org/10.1007/BF02070486

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  • DOI: https://doi.org/10.1007/BF02070486

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