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A new method to determine the distance of electron tunneling transfer and its application to recombination of paramagnetic radiation deffects in CaO

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Abstract

A new method to determine the distance of electron tunneling transfer between paramagnetic reagents based on simultaneous analysis of both kinetic and ESR data is suggested. This method has been used to estimate the tunneling distance and the parameters characterizing the rate of tunneling for finely dispersed CaO.

Abstract

Предложен новый метод оценки расстояния туннельного переноса электрона между парамагнитными реагентами, основанный на совместном использо-вании кинетической и спектральной информации. С его помощью в высокодисперсной CaO оценены расстояния туннелирования и значения параметров, характеризующих скорость туннелирования.

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Aristov, Y.I., Parmon, V.N. A new method to determine the distance of electron tunneling transfer and its application to recombination of paramagnetic radiation deffects in CaO. React Kinet Catal Lett 27, 259–262 (1985). https://doi.org/10.1007/BF02070453

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  • DOI: https://doi.org/10.1007/BF02070453

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