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Reaction Kinetics and Catalysis Letters

, Volume 45, Issue 2, pp 235–241 | Cite as

Rate sensitivity analysis of a model of the Briggs-Rauscher reaction

  • T. Turányi
Article

Abstract

An updated mechanism for the Briggs-Rauscher reaction (also known as “Iodine Clock” reaction) has been investigated by the principal component analysis of the rate sensitivity matrix. The analysis revealed that five reactions of the 15-step model were redundant. The results of principal component and of rate-of-production analyses together gave an insight into the basic processes of the “Iodine Clock” reaction.

Keywords

Physical Chemistry Principal Component Analysis Sensitivity Analysis Catalysis Iodine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Современный механизм реакции Бригса-Раушера (известной также как реакция “иодных часов”) был исследован с помощью принципиального компонентного анализа матрицы чуствительности реакции. Анализ подтверждает, что 5 реакций из 15и-ступенчатой модели можно считать излишними. Результаты анализа принципиального компонента и скорости получения вместе дают более глубокие представления о механизме реакции “иодных часов”.

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Copyright information

© Akadémiai Kiadó 1991

Authors and Affiliations

  • T. Turányi
    • 1
  1. 1.Central Research Institute for Chemistry of the Hungarian Academy of SciencesBudapestHungary

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