Advertisement

Reaction Kinetics and Catalysis Letters

, Volume 9, Issue 1, pp 47–52 | Cite as

The structure of amines and their catalytic activity in the copolymerization of epoxides with cyclic anhydrides

  • J. Lustom
  • Z. Mamásek
Article
  • 25 Downloads

Abstract

The copolymerization of epoxides with cyclic anhydrides has been studied using the reaction of 2-hydroxy-4-(2,3-epoxypropoxy)benzophenone with phthalic anhydride in o-xylene catalyzed by different amines as a model reaction. The rate constants of copolymerization have been determined and the influence of the amine structure on the catalytic activity is discussed.

Keywords

Physical Chemistry Catalysis Catalytic Activity Anhydride Epoxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Сополимеризация эпоксидов с циклическими ангидридами была исследована на модельной реакции 2-гидрокси-4-(2,3-эпоксипропокси) бензофенона с фталевымангидридом в о-ксилоле, катализированной различными аминами. Были определены константы скорости сополимеризации и обсуждается влияние структуры амина на его каталитичеслую активность в процессе сополимеризации.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M. F. Sorokin, L. G. Shode: Lakokrasochn. Mater. Primen., 76, (1968);CA 68, 87768 g.Google Scholar
  2. 2.
    Y. Tanaka, H. Kakiuchi: J. Appl. Polym. Sci.,7, 1063 (1963).Google Scholar
  3. 3.
    R. J. Arnold: Mod. Plast.,41, 149 (1964).Google Scholar
  4. 4.
    J. Lustoň, Z. Manásek, M. Kuličkova: J. Macromol. Sci., submitted.Google Scholar
  5. 5.
    J. A. Riddick, W. B. Bunger: Organic Solvents, Wiley-Interscience, New York 1970.Google Scholar
  6. 6.
    S. V. Bogatkov, A. F. Popov, L. M. Litvinenko: Reakts. Sposobn. Org. Soedin.,6, 1011 (1969).Google Scholar
  7. 7.
    A. Hilt, J. Trivedi, K. Hammann: Makromol. Chem.,89, 177 (1965).Google Scholar
  8. 8.
    R. F. Fischer: J. Polym. Sci.,44, 155 (1960).Google Scholar
  9. 9.
    L. Schechter, J. Wynstra, R. F. Kurkjy: Ind. Eng. Chem.,48, 94 (1956).Google Scholar
  10. 10.
    F. B. Alvey: J. Appl. Polym. Sci.,13, 1473 (1969).Google Scholar
  11. 11.
    J. G. Pritchard, I. A. Siddiqui: J. Chem. Soc. Perkin Trans., II, 1309 (1972).Google Scholar

Copyright information

© Akadémiai Kiadó 1978

Authors and Affiliations

  • J. Lustom
    • 1
  • Z. Mamásek
    • 1
  1. 1.Institute of Polymers, Slovak Academy of SciencesBratislavaCzechoslovakia

Personalised recommendations