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Selective cation exchange separation of bismuth on zirconium hexacyanoferrate(III) column

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Abstract

A new inorganic ion exchanger, zirconium hexacyanoferrate(III) prepared by adding potassium hexacyanoferrate(III) to zirconium oxychloride at 80°C has been found to be stable in acids and salt solutions. Distribution coefficient values determined for various metal ions show that the exchanger has a high affinity for bismuth. Binary separations of Bi(III) from a number of other metal ions at different concentrations were achieved on the column of the exchanger. Thus the exchanger has been found useful for the separation of bismuth from a large number of metals.

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Authors and Affiliations

  1. Department of Chemistry, University of Roorkee, 247 667, Roorkee, India

    A. K. Jain, R. P. Singh & C. Bala

Authors
  1. A. K. Jain
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  2. R. P. Singh
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  3. C. Bala
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Jain, A.K., Singh, R.P. & Bala, C. Selective cation exchange separation of bismuth on zirconium hexacyanoferrate(III) column. Journal of Radioanalytical and Nuclear Chemistry, Articles 89, 3–11 (1985). https://doi.org/10.1007/BF02070198

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  • DOI: https://doi.org/10.1007/BF02070198

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