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Formation of alkyl peroxides in oxidation of alkanes by H2O2 catalyzed by transition metal complexes

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Abstract

Some reactions between alkanes and H2O2 in the presence of transition metal compounds, e.g. Cr(VI), V(V), Mn(III), Pd(II), Fe(II), yield alkyl hydroperoxides as main products.

Abstract

Некоторые реакции алканов с H2O2 в присутствии соединений переходных металлов, например, Cr(VI), V(V), Mn(III), Pd(II), Fe(II), приводят к образованию алкилгидропероксидов в качестве основных продуктов.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, 117977, Moscow, Russia

    G. B. Shulpin & G. V. Nizova

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  1. G. B. Shulpin
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  2. G. V. Nizova
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Shulpin, G.B., Nizova, G.V. Formation of alkyl peroxides in oxidation of alkanes by H2O2 catalyzed by transition metal complexes. React Kinet Catal Lett 48, 333–338 (1992). https://doi.org/10.1007/BF02070104

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  • DOI: https://doi.org/10.1007/BF02070104

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