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Reaction Kinetics and Catalysis Letters

, Volume 48, Issue 1, pp 291–294 | Cite as

Cationic Pd(II)-complex formation in the Pd(acac)2-Et2NH-BF3−OET2 system and its activity in butadiene-amine telomerization

  • M. L. Chernyshev
  • V. S. Tkach
  • T. V. Dmitrieva
  • G. V. Ratovskii
  • S. V. Zinchenko
  • F. K. Shmidt
Article

Abstract

Pd(acac)2 reacts with Et2NH and BF3OEt2 to produce [(acac) Pd(Et2NH)2]BF4. This complex is highly active in butadiene-secondary amine telomerization reactions.

Keywords

Physical Chemistry Catalysis Complex Formation Acac Telomerization 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Pd(acac)2 реагирует с Et2NH и BF3OEt2, образуя [(acac) Pd(Et2NH)2]BF4. Выделенный комплекс показал высокую активность в реакциях теломеризации бутадиена с аминами.

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References

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Copyright information

© Akadémiai Kiadó 1992

Authors and Affiliations

  • M. L. Chernyshev
    • 1
  • V. S. Tkach
    • 1
  • T. V. Dmitrieva
    • 1
  • G. V. Ratovskii
    • 1
  • S. V. Zinchenko
    • 1
  • F. K. Shmidt
    • 1
  1. 1.State UniversityIrkutskRussia

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