Reaction Kinetics and Catalysis Letters

, Volume 48, Issue 1, pp 291–294 | Cite as

Cationic Pd(II)-complex formation in the Pd(acac)2-Et2NH-BF3−OET2 system and its activity in butadiene-amine telomerization

  • M. L. Chernyshev
  • V. S. Tkach
  • T. V. Dmitrieva
  • G. V. Ratovskii
  • S. V. Zinchenko
  • F. K. Shmidt
Article

Abstract

Pd(acac)2 reacts with Et2NH and BF3OEt2 to produce [(acac) Pd(Et2NH)2]BF4. This complex is highly active in butadiene-secondary amine telomerization reactions.

Keywords

Physical Chemistry Catalysis Complex Formation Acac Telomerization 

Abstract

Pd(acac)2 реагирует с Et2NH и BF3OEt2, образуя [(acac) Pd(Et2NH)2]BF4. Выделенный комплекс показал высокую активность в реакциях теломеризации бутадиена с аминами.

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References

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Copyright information

© Akadémiai Kiadó 1992

Authors and Affiliations

  • M. L. Chernyshev
    • 1
  • V. S. Tkach
    • 1
  • T. V. Dmitrieva
    • 1
  • G. V. Ratovskii
    • 1
  • S. V. Zinchenko
    • 1
  • F. K. Shmidt
    • 1
  1. 1.State UniversityIrkutskRussia

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