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Cationic Pd(II)-complex formation in the Pd(acac)2-Et2NH-BF3−OET2 system and its activity in butadiene-amine telomerization

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Abstract

Pd(acac)2 reacts with Et2NH and BF3OEt2 to produce [(acac) Pd(Et2NH)2]BF4. This complex is highly active in butadiene-secondary amine telomerization reactions.

Abstract

Pd(acac)2 реагирует с Et2NH и BF3OEt2, образуя [(acac) Pd(Et2NH)2]BF4. Выделенный комплекс показал высокую активность в реакциях теломеризации бутадиена с аминами.

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References

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Authors and Affiliations

  1. State University, 664003, Irkutsk, Russia

    M. L. Chernyshev, V. S. Tkach, T. V. Dmitrieva, G. V. Ratovskii, S. V. Zinchenko & F. K. Shmidt

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  1. M. L. Chernyshev
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  2. V. S. Tkach
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  3. T. V. Dmitrieva
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  4. G. V. Ratovskii
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  5. S. V. Zinchenko
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  6. F. K. Shmidt
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Chernyshev, M.L., Tkach, V.S., Dmitrieva, T.V. et al. Cationic Pd(II)-complex formation in the Pd(acac)2-Et2NH-BF3−OET2 system and its activity in butadiene-amine telomerization. React Kinet Catal Lett 48, 291–294 (1992). https://doi.org/10.1007/BF02070098

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  • DOI: https://doi.org/10.1007/BF02070098

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