Reaction Kinetics and Catalysis Letters

, Volume 48, Issue 1, pp 255–257 | Cite as

Solvent effect on transformation kinetics of ozone and toluene complex

  • R. K. Yanbaev
  • V. V. Shereshovets
  • V. D. Komissarov
Article

Abstract

Medium effect on the decomposition rate of C6H5CH3.O3 in solvents: n-C6H14, CHCl3, CH2Cl2, (CH3)2CO, CH3OH and CH3CN has been studied. Consumption rate of this complex increases in polar solvents.

Keywords

Physical Chemistry Ozone Toluene Catalysis CH2Cl2 

Abstract

Рассмотрено влияние среды на скорость распада C6H5CH3.O3 в растворителях n-C6H14, CHCl3, CH2Cl2, (CH3)2CO, CH3OH, CH3CN. В полярных растворителях скорость расходования комплекса увеличивается.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    P.S. Bailey, J.W. Ward, R.E. Hornish: J. Am. Chem. Soc.,93, 3552 (1971).Google Scholar
  2. 2.
    P.S. Bailey, J.W. Ward, T.P. Carter, E. Nich, C.M. Fischer, A.-I. Y. Khashab: J. Am. Chem. Soc.,96, 6136 (1974).Google Scholar
  3. 3.
    V.V. Shereshovets, L.G. Galimova, V.D. Komissarov: Izv. Akad. Nauk SSSR, Ser. khim., 2488 (1981).Google Scholar
  4. 4.
    V.V. Shereshovets, N.M. Korotaeva, I.M. Kiateva, V.D. Komissarov, G.A. Tolstikov: React. Kinet. Catal. Lett.,32, 443 (1986).Google Scholar
  5. 5.
    W.A. Pryor, N. Ohto, D.F. Church: J. Am. Chem. Soc.,104, 5813 (1982).Google Scholar

Copyright information

© Akadémiai Kiadó 1992

Authors and Affiliations

  • R. K. Yanbaev
    • 1
  • V. V. Shereshovets
    • 1
  • V. D. Komissarov
    • 1
  1. 1.Institute of Organic ChemistryUfaRussia

Personalised recommendations