Reaction Kinetics and Catalysis Letters

, Volume 48, Issue 1, pp 49–54 | Cite as

Effect of molybdenum catalysis on the perborate-bromide reaction. Kinetics and mechanism and some theoretical considerations

  • B. F. Shraydeh
  • G. Svehla


In the presence of molybdenum, both the uncatalyzed and the catalyzed reactions proceed simultaneously. An equation for kcat was derived and the effect of temperature was described through a temperature function F(T) by the use of the Arrhenius-Eyring equation. A plausible mechanism is postulated and the theoretical background given for the analytical application of molybdenum.


Physical Chemistry Catalysis Molybdenum Catalyze Reaction Theoretical Background 


В присутствии молибдена протекают одновременно катализированные и некатализированные реакции. Получено уравнение для kcat, а влияние темлературы описывали с помощью уравнения Аррениуса-Айринга. Постулировали вероятный механизм реакции и приводятся теоретические основы для аналитического использования молибдена.


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  1. 1.
    B.F. Shraydeh, G. Svehla: Anal. Lett., 25 (6) (1992).Google Scholar
  2. 2.
    A.J. Dedman, T.J. Lewis, D.H. Richards: J. Chem. Soc., 2456 (1963)Google Scholar
  3. 3.
    R. Pizer, C. Tihal: Inorg. Chem.26, 3639 (1987).Google Scholar
  4. 4.
    A.M. Held, D.J. Halko, J.K. Hurst: J. Am. Chem. Soc.,100, 5732 (1978).Google Scholar
  5. 5.
    B.F. Shraydeh, G. Svehla: React. Kinet. Catal. Lett.,48, 43 (1992).Google Scholar

Copyright information

© Akadémiai Kiadó 1992

Authors and Affiliations

  • B. F. Shraydeh
    • 1
  • G. Svehla
    • 2
  1. 1.Chemistry Department, Faculty of ScienceAn-Najah National UniversityNablus-West Bank
  2. 2.Chemistry DepartmentUniversity College CorkIreland

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