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Effect of molybdenum catalysis on the perborate-bromide reaction. Kinetics and mechanism and some theoretical considerations

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Abstract

In the presence of molybdenum, both the uncatalyzed and the catalyzed reactions proceed simultaneously. An equation for kcat was derived and the effect of temperature was described through a temperature function F(T) by the use of the Arrhenius-Eyring equation. A plausible mechanism is postulated and the theoretical background given for the analytical application of molybdenum.

Abstract

В присутствии молибдена протекают одновременно катализированные и некатализированные реакции. Получено уравнение для kcat, а влияние темлературы описывали с помощью уравнения Аррениуса-Айринга. Постулировали вероятный механизм реакции и приводятся теоретические основы для аналитического использования молибдена.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, An-Najah National University, Nablus-West Bank

    B. F. Shraydeh

  2. Chemistry Department, University College Cork, Ireland

    G. Svehla

Authors
  1. B. F. Shraydeh
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  2. G. Svehla
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Shraydeh, B.F., Svehla, G. Effect of molybdenum catalysis on the perborate-bromide reaction. Kinetics and mechanism and some theoretical considerations. React Kinet Catal Lett 48, 49–54 (1992). https://doi.org/10.1007/BF02070066

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  • DOI: https://doi.org/10.1007/BF02070066

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