Reaction Kinetics and Catalysis Letters

, Volume 48, Issue 1, pp 49–54 | Cite as

Effect of molybdenum catalysis on the perborate-bromide reaction. Kinetics and mechanism and some theoretical considerations

  • B. F. Shraydeh
  • G. Svehla


In the presence of molybdenum, both the uncatalyzed and the catalyzed reactions proceed simultaneously. An equation for kcat was derived and the effect of temperature was described through a temperature function F(T) by the use of the Arrhenius-Eyring equation. A plausible mechanism is postulated and the theoretical background given for the analytical application of molybdenum.


Physical Chemistry Catalysis Molybdenum Catalyze Reaction Theoretical Background 
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В присутствии молибдена протекают одновременно катализированные и некатализированные реакции. Получено уравнение для kcat, а влияние темлературы описывали с помощью уравнения Аррениуса-Айринга. Постулировали вероятный механизм реакции и приводятся теоретические основы для аналитического использования молибдена.


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Copyright information

© Akadémiai Kiadó 1992

Authors and Affiliations

  • B. F. Shraydeh
    • 1
  • G. Svehla
    • 2
  1. 1.Chemistry Department, Faculty of ScienceAn-Najah National UniversityNablus-West Bank
  2. 2.Chemistry DepartmentUniversity College CorkIreland

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