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Specific changes in the activity of titanium carbides with various Ti/C ratios in propylene hydrogenation

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Abstract

According to X ray emission spectra, the established regularity in the activity change for titanium carbides with various Ti/C ratios is attributed to the filling degree of the t2g states of titanium atoms determining the metallicity of chemical bonds of the compounds.

Abstract

Установленная закономерность изменения активности карбидов титана с различным отношением Ti/C объяснена на основании данных рентгеновских эмиссионных спектров степенью заполнения t2g состояний атома титана, обуславливающих металличность химической связи соединения.

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Authors and Affiliations

  1. Institute of Materials Science, Kiev, USSR

    A. I. Kharlamov, V. P. Krivitskii & N. D. Lemeshko

Authors
  1. A. I. Kharlamov
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  2. V. P. Krivitskii
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  3. N. D. Lemeshko
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Kharlamov, A.I., Krivitskii, V.P. & Lemeshko, N.D. Specific changes in the activity of titanium carbides with various Ti/C ratios in propylene hydrogenation. React Kinet Catal Lett 17, 63–67 (1981). https://doi.org/10.1007/BF02069517

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  • DOI: https://doi.org/10.1007/BF02069517

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