Abstract
The interatomic potentials in the system (alkali atom in the ground and excited states)—((mercury atom) are calculated on the basis of the effective pseudopotential method using a new form of the polarized interaction potential obtained from calculations of the most important polarization patterns of perturbation theory in the Thomas-Fermi approximation. This method is used to calculate the intermolecular terms of the system A-Hg (A=K, Fr), some of which have been obtained previously.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. V. Glushkov, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 6, 31–38 (1994).
A. V. Glushkov, Opt. Spektrosk.,77, No. 1, 885–890 (1994).
A. V. Glushkov, Zh. Fiz. Khim.,66, No. 6, 1259–1268 (1992).
A. A. Radtsig and B. M. Smirnov, Handbook of Atomic and Molecular Physics [in Russian], Énergoatomizdat, Moscow (1986).
E. E. Nikitin and S. Ya. Umanskii, Semiempirical Methods for the Calculation of Atomic Interaction Potentials, Progress in Science and Technology: Molecular Structure and Chemical Bond Series [in Russian], No. 4 (1980).
G. K. Ivanov, Teor. Éksp. Khim.,14, No. 1, 110–115 (1979);15, No. 1, 44–50 (1979).
P. Durand and J. P. Malrieu, in:Ab initio Methods of Quantum Chemistry, K. P. Lawley (ed.), Wiley, New York (1987).
A. Z. Devdariani and A. L. Zagrebin, in: Plasma Chemistry [in Russian], No. 15, B. M. Smirnov (ed.), Moscow (1989), pp. 44–93.
U. Buck, Rev. Mod. Phys.,46, 369–394 (1974).
A. L. Zagrebin and S. I. Tserkovnyi, Khim. Fiz.,10, 595–606 (1991).
F. Masnou-Seeuws and A. Henriet, J. Phys. B,21, No. 12, L338–L346.
W. E. Baylis, J. Chem. Phys.,51, 2665–2674 (1969).
D. Duren, Chem. Phys. Lett.,39, No. 3, 481–485 (1976).
C. Bottcher and A. Dalgarno, Proc. R. Soc. London Ser. A,340, 187–196 (1974).
I. G. Kaplan, Introduction to the Theory of Intermolecular Interactions [in Russian], Nauka, Moscow (1982).
P. Gombas, Pseudopotentiale, Springer-Verlag, Berlin (1967).
V. V. Tolmachev, Adv. Chem. Phys.,14, 421–482 (1969).
V. V. Tolmachev, L. N. Ivanov, and E. P. Ivanova, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 12, 84–89 (1969).
V. S. Letochov and L. N. Ivanov, Comments At. Mol. Phys. D, No. 4, 169–192 (1985).
E. P. Ivanova, L. N. Ivanov, A. V. Glushkov, and A. E. Kramida, Phys. Scr.,32, No. 4, 512–524 (1985).
A. V. Glushkov and E. P. Ivanova, J. Quant. Spectrosc. Radiat. Transfer,36, No. 2, 127–145 (1986).
A. V. Glushkov, Zh. Strukt. Khim.,29, No. 4, 3–10 (1988);,31, No. 1, 13–18 (1990).
A. V. Glushkov, Zh. Fiz. Khim.,63, No. 11, 2894–2898 (1989);66, No. 4, 589–595 (1992).
D. R. Bates, K. Ledsham, and A. L. Stewart, Philos. Trans. R. Soc. London Ser. A,246, No. 911, 215–246 (1953).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 84–88, January, 1996.
Rights and permissions
About this article
Cite this article
Glushkov, A.V., Ambrosov, S.V., Orlova, V.É. et al. Calculation of the potential of interaction of excited atoms of alkali elements with a mercury atom: A-Hg interaction (A=K, Fr). Russ Phys J 39, 77–80 (1996). https://doi.org/10.1007/BF02069246
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02069246