Reaction Kinetics and Catalysis Letters

, Volume 34, Issue 1, pp 75–80 | Cite as

Parametric analysis of eigenvalues of matrices corresponding to linear one-route catalytic reaction mechanism

  • A. N. Bocharov
  • V. I. Bykov


The parametric analysis of accepted eigenvalues of matrices observed in chemical kinetics and corresponding to the linear n-stage one-route mechanisms with irreversible stages has been conducted. Relaxation times with varying one of the rate constants are given. The possibility of nonmonotonic change of relaxation times with growing rate constants is shown.


Physical Chemistry Catalysis Relaxation Time Reaction Mechanism Catalytic Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Проведен параметрический анализ собственных значений матриц, возникающих в химической кинетике и отвечающих линейным n-стадийным одномаршрутным механизмам с необратимыми стадиями. Даны оценки времен релаксации при варьировании одной иэ констант скорости стадии. Показана возможность немонотонного изменения времени релаксации при росте констант скорости.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    M.I. Temkin: Kinet. Katal.,17, 1095 (1976)Google Scholar
  2. 2.
    V.M. Cheresiz, G.S. Yablonskii: React. Kinet. Catal. Lett.,22, 69 (1983)Google Scholar
  3. 3.
    B.V. Alekseev, N.I. Koltsov: React. Kinet. Catal. Lett.,22, 63 (1983)Google Scholar
  4. 4.
    G.S. Yablonskii, V.M. Cheresiz: React. Kinet. Catal. Lett.,24, 49 (1984)Google Scholar
  5. 5.
    B.V. Alekseev, N.I. Koltsov, S.L. Kiperman: Theor. Eksper. Khim.,19, 188 (1983)Google Scholar

Copyright information

© Akadémiai Kiadó 1987

Authors and Affiliations

  • A. N. Bocharov
    • 1
  • V. I. Bykov
    • 1
  1. 1.Computing CenterKrasnoyarskUSSR

Personalised recommendations