Reaction Kinetics and Catalysis Letters

, Volume 34, Issue 1, pp 75–80 | Cite as

Parametric analysis of eigenvalues of matrices corresponding to linear one-route catalytic reaction mechanism

  • A. N. Bocharov
  • V. I. Bykov
Article

Abstract

The parametric analysis of accepted eigenvalues of matrices observed in chemical kinetics and corresponding to the linear n-stage one-route mechanisms with irreversible stages has been conducted. Relaxation times with varying one of the rate constants are given. The possibility of nonmonotonic change of relaxation times with growing rate constants is shown.

Keywords

Physical Chemistry Catalysis Relaxation Time Reaction Mechanism Catalytic Reaction 

Abstract

Проведен параметрический анализ собственных значений матриц, возникающих в химической кинетике и отвечающих линейным n-стадийным одномаршрутным механизмам с необратимыми стадиями. Даны оценки времен релаксации при варьировании одной иэ констант скорости стадии. Показана возможность немонотонного изменения времени релаксации при росте констант скорости.

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Copyright information

© Akadémiai Kiadó 1987

Authors and Affiliations

  • A. N. Bocharov
    • 1
  • V. I. Bykov
    • 1
  1. 1.Computing CenterKrasnoyarskUSSR

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