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Contribution of one-electron acceptor centers to oxidative dimerization of methane

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Abstract

The ESR method was used to identify paramagnetic centers in the Pb−Mg oxide system and to study its catalytic properties in oxidative dimerization of methane. Reaction rate is shown to correlate well with the presence of one-electron acceptor centers in the sample.

Abstract

Методом ЭПР-спектроскопии идентифицированы парамагнитные центры в Pb−Mg оксидной системе и изучены ее каталитические свойства в реакции окислительной димеризации метана. Показано, что скорость реакции хорошо коррелирует с наличием в образце одноэлектронных акцепторных центров.

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References

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    A. I. Suleimanov, S. M. Aliev & V. D. Sokolovskii

  2. Institute of Petrochemical Processes, Baku, USSR

    E. G. Ismailov

Authors
  1. A. I. Suleimanov
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  2. E. G. Ismailov
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  3. S. M. Aliev
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  4. V. D. Sokolovskii
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Suleimanov, A.I., Ismailov, E.G., Aliev, S.M. et al. Contribution of one-electron acceptor centers to oxidative dimerization of methane. React Kinet Catal Lett 34, 51–55 (1987). https://doi.org/10.1007/BF02069200

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  • DOI: https://doi.org/10.1007/BF02069200

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