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Hyperfine Interactions

, Volume 90, Issue 1, pp 121–134 | Cite as

Mössbauer effect and TEM in mineralogy

  • E. A. Ferrow
Invited Papers

Abstract

Mössbauer effect (ME) provides useful information on oxidation state, co-ordination number, co-ordination state, site occupancies, and magnetic properties of Fe-bearing phases. The information gained by ME together with the information provided by other conventional techniques is used to extract temperature, pressure, and kinetics of rockforming processes. Nevertheless, ME requires that the phases studied are homogeneous over an extremely large volume and that Fe is a major component of the system. Transmission electron microscopy (TEM), on the other hand, provides similar information over a very small volume for a system of any component. However, present TEM spectrometers do not provide sufficient resolution to detect the mixed oxidation state. A complete characterisation of phases in rocks requires, therefore, that conventional techniques be combined with TEM.

Keywords

Oxidation Thin Film Transmission Electron Microscopy Magnetic Property Large Volume 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. [1]
    G.M. Bancroft, Chem. Geol. 5(1969)255.Google Scholar
  2. [2]
    F.C. Hawthorne, Mössbauer Spectroscopy, in:Spectroscopic Methods in Mineralogy and Geology, ed. F.C. Hawthorne (MSA, 1988) p. 698.Google Scholar
  3. [3]
    F. Seifert, Phys. Chem. Miner. 77(1977)43.Google Scholar
  4. [4]
    E.A. Ferrow and M. Ripa, Min. Mag. 54(1990)547.Google Scholar
  5. [5]
    R. Smyth and T.C. McCormick, Ultramicrosc. 26(1988)77.Google Scholar
  6. [6]
    J.C.H. Spence, Techniques closely related to high-resolution electron microscopy, in:High-Resolution Transmission Electron Microscopy, eds. P.R. Buseck, J.M. Cowley and L. Eyring (Oxford University Press, New York, 1988) p. 645.Google Scholar
  7. [7]
    P.R. Buseck and P. Self, Electron energy-loss spectroscopy (EELS) and electron channelling (ALCHEMI), in:Minerals and Reactions at the Atomic Scale: Transmission Electron Microscopy, ed. P.R. Buseck (BookCrafters, Chelsea, 1992) p. 508.Google Scholar
  8. [8]
    M.T. Otten, Phillips Electron Opt. Bull. 126(1989)21.Google Scholar
  9. [9]
    J. Taftö and J.C.H. Spence, Science 218(1982)49.Google Scholar
  10. [10]
    A.G. Nord, H. Annersten and A. Filippidis, Am. Miner. 67(1982)1206.Google Scholar
  11. [11]
    H. Annersten, T. Ericsson and A. Filippidis, Am. Miner. 67(1982)1212.Google Scholar
  12. [12]
    H. Annersten, J. Adetungi and A. Filippides, Am. Miner. 69(1984)1110.Google Scholar
  13. [13]
    J.M. Ferry and F.S Spear, Contrib. Miner. Petrol. 66(1978)113.Google Scholar
  14. [14]
    T.M. Otten and P.R. Buseck, Phys. Chem. Miner. 14(1987)45.Google Scholar
  15. [15]
    E.A. Ferrow, Phys. Chem. Miner. 14(1987)270.Google Scholar
  16. [16]
    G.J. Redhammer, E. Dachs and G. Amthauer, Terra Abstracts 5(1993)510.Google Scholar
  17. [17]
    F. Lungelhofer, E. Dachs, F. Finger and G. Amthauer, Terra Abstracts 5(1993)509.Google Scholar
  18. [18]
    S. Sklavounos, Neues Jahrbuch Miner. Mh8(1992)377.Google Scholar
  19. [19]
    M.D. Dyar and R.G. Burns, Am. Miner. 71(1986)951.Google Scholar
  20. [20]
    D.G. Rancourt, I.A.D. Christie, M. Royer, H. Kodama, J.L. Robert, A.E. Lalonde and E. Murad, Am. Miner. 79(1994)51.Google Scholar
  21. [21]
    J.H. Rask, B.A. Miner and P.R. Buseck, Ultramicrosc. 21(1987)321.Google Scholar
  22. [22]
    J.-O. Bovin, Micron Microsc. Acta 23(1992)145.Google Scholar
  23. [23]
    A.D. Law, Min. Mag. 53(1989)181.Google Scholar
  24. [24]
    E.A. Ferrow, D. London, K.S. Goodman and D.R. Veblen, Contrib. Miner. Petrol. 105(1990)491.Google Scholar
  25. [25]
    E.A. Ferrow and M. Ripa, Lithos 26(1991)271.Google Scholar
  26. [26]
    D.R. Veblen and J.M. Ferry, Am. Miner. 68(1983)1160.Google Scholar
  27. [27]
    L. Heller-Kellai and I. Rozenson, Phys. Chem. Miner. 7(1981)223.Google Scholar
  28. [28]
    C.V. Guidotti, Micas in metamorphic rocks, in:Micas, ed. S.W. Bailey (MSA, 1984) p. 357.Google Scholar
  29. [29]
    D.R. Veblen, E.A. Ferrow, E.A. Smelik and J.-E. Lindqvist, in preparation.Google Scholar
  30. [30]
    E.A. Ferrow, L.R. Wallenberg and H. Skogby, Eur. J. Miner. 5(1993)479.Google Scholar
  31. [31]
    E.A. Ferrow, these Proceedings, Hyp. Int.Google Scholar
  32. [32]
    E.A. Ferrow, H. Annersten and R. Gundawardane, Min. Mag. 52(1988)221.Google Scholar
  33. [33]
    B. Baginski and E.A. Ferrow, Terra Abstracts 5(1993)398.Google Scholar
  34. [34]
    L. Heller-Kellai and I. Rozenson, Clays and Clay Miner. 28(1980)355.Google Scholar

Copyright information

© J.C. Baltzer AG, Science Publishers 1994

Authors and Affiliations

  • E. A. Ferrow
    • 1
  1. 1.Department of Mineralogy and PetrologyLund UniversityLundSweden

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