Skip to main content
SpringerLink
Log in

Collisional energy transfer in the two-channel decomposition of 1,1,2,2-tetrafluorocyclobutane and 1-methyl-2,2,3,3-tetrafluorocyclobutane, II. Gas/wall collisions

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The efficiency of gas/wall vibrational energy transfer has been studied over the temperature range 800–1100 K by the “variable encounter” method. The average energies transferred per deactiviting collisions with the wall were determined at 800 K to be 3200 cm−1 and 2900 cm−1 for the 1,1,2,2-tetrafluorocyclobutane (TFCB) and 1-methyl-2,2,3,3-tetrafluorocyclobutane (MTFCB) molecules, respectively. This energy increased strongly with decreasing temperature. A comparison is made of <ΔE′> with previous results for related molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. Chow, D.J. Wilson: J. Phys. Chem.,66, 342 (1982).

    Google Scholar 

  2. L. Zalotai, T. Turányi, T. Bérces, F. Márta: React. Kinet. Catal. Lett.,51, 401 (1993).

    Google Scholar 

  3. L. Zalotai, T. Bérces, F. Márta: React. Kinet. Catal. Lett.,40, 41 (1989); L. Zalotai, T. Bérces, F. Márta: J. Chem. Soc. Faraday Trans.,86, 21 (1990).

    Google Scholar 

  4. D.F. Kelley, L. Zalotai, B.S. Rabinovitch: Chem. Phys.,46, 379 (1990).

    Google Scholar 

  5. D.C. Tardy, B.S. Rabinovitch: Chem. Rev.,77, 369 (1977).

    Google Scholar 

  6. D.C. Tardy, B.S. Rabinovitch: J. Chem. Phys.,48, 1282 (1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Central Research Institute for Chemistry, Hungarian Academy of Sciences, Pusztaszeri út 59-67, 1025, Budapest, Hungary

    L. Zalotai, T. Turányi, T. Bérces & F. Márta

Authors
  1. L. Zalotai
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Turányi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. Bérces
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. F. Márta
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zalotai, L., Turányi, T., Bérces, T. et al. Collisional energy transfer in the two-channel decomposition of 1,1,2,2-tetrafluorocyclobutane and 1-methyl-2,2,3,3-tetrafluorocyclobutane, II. Gas/wall collisions. React Kinet Catal Lett 51, 409–414 (1993). https://doi.org/10.1007/BF02069085

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02069085

Keywords

Search

Navigation