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Reaction Kinetics and Catalysis Letters

, Volume 51, Issue 2, pp 269–277 | Cite as

Monte-Carlo studies of trigger self-oscillations in a bimolecular heterogeneous catalytic reaction

  • L. V. Lutsevich
  • V. I. Elokhin
  • G. S. Yablonskii
Article

Abstract

Dynamics of processes on metal surfaces and conditions for rate oscillations taking into account reconstruction of the catalyst are investigated using the Monte-Carlo method for a catalytic reaction following the Langmuir-Hinshelwood mechanism. Different regions of the oscillations were found, particularly the region where the oscillations are governed by the formation of a steady compact cluster which controls the frequency and amplitude of oscillations.

Keywords

Physical Chemistry Catalysis Metal Surface Catalytic Reaction Compact Cluster 
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Copyright information

© Akadémiai Kiadó 1993

Authors and Affiliations

  • L. V. Lutsevich
  • V. I. Elokhin
    • 1
  • G. S. Yablonskii
  1. 1.Boreskov Institute of CatalysisNovosibirskRussia

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