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Reaction Kinetics and Catalysis Letters

, Volume 29, Issue 2, pp 417–421 | Cite as

Kinetics of the ĊH3+CH3CO 2 →CH4+ĊH2CO 2 reaction in single crystals of NaAc·3H2O having different isotopic compositions

  • V. M. Syutkin
  • V. A. Tolkatchev
Article

Abstract

The kinetics of the ĊH3+CH3CO 2 →CH4+ĊH2CO 2 reaction at T∼140 K in NaAc·3H2O lattice constituted by CH3CO2Na+CD3CO2Na mixture has been studied by the ESR method. It has been established that the reaction proceeds under high mobility of reactants and its kinetics is described on the basis of rate constant distribution.

Keywords

Physical Chemistry 3H2O Catalysis Isotopic Composition High Mobility 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Методом ЭПР при T∼140 K изучена кинетика реакции CH3+CH3CO 2 →CH4+ĊH2CO 2 в решетке NaAc·3H2O состоящей из смеси молекул CH3CO2Na и CD3CO2Na. Показано, что реакция протекает в условиях значительной подвижности реагентов и кинетика описывается на основе распределения по константам скоростей.

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Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • V. M. Syutkin
    • 1
  • V. A. Tolkatchev
    • 1
  1. 1.Institute of Chemical Kinetics and CombustionNovosibirskUSSR

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