Reaction Kinetics and Catalysis Letters

, Volume 29, Issue 2, pp 323–330 | Cite as

Characterization of coke by hydrogen and carbon analysis

  • J. Barbier
  • E. Churin
  • J. M. Parera
  • J. Riviere


Coke deposited on heterogeneous catalysts can be characterized by temperature programmed oxidation. The comparison between the amount of CO2 produced and the amount of O2 consumed gives the ratio H/C. For Pt/Al2O3 catalysts it has been shown that coke deposited on the metal is less dehydrogenated than coke deposited on the support.


Oxidation Hydrogen Physical Chemistry Catalysis Heterogeneous Catalyst 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Отложение кокса на гетерогенных катализаторах характеризуют температурно-программированным окислением. Сравнением количества образующегося CO2 с количеством израсходаванного O2 получают отношение H/C. Показано, что в случае катализатора Pt/Al2O3 углерод на металле менее дегидрировах, чем углерод на носителе.


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  1. 1.
    J. Barbier, P. Marecot, N. Martin, L. Elassal, R. Maurel: Stud. Surf. Sci. Catal.,6, 53 (1980)Google Scholar
  2. 2.
    P. P. Lankhorst, H. C. De Jongste, V. Ponec: Stud. Surf. Sci. Catal.,6, 43 (1980)Google Scholar
  3. 3.
    J. Barbier, L. Elassal, N. S. Gnep, M. Guisnet, W. Molina, Y. Zhang: Bull. Soc. Chim. (in press)Google Scholar
  4. 4.
    J. M. Parera, N. S. Figoli, J. N. Beltramini, E. J. Churin, R. A. Cabrol: Proc. 8th International Congress on Catal., Vol. 2, p. 593, 1984Google Scholar
  5. 5.
    W. G. Appleby, J. W. Gibson, G. M. Good: Ind. Eng. Process.,1, 102 (1962)Google Scholar
  6. 6.
    C. G. Ruberhausen, C. C. Watson: Chem. Eng. Sci.,3, 110 (1954)Google Scholar
  7. 7.
    P. E. Eberly, C. N. Kimberlin, W. H. Miller, H. V. Brushel: Ind. Eng. Chem. Proc.,5, 193 (1966)Google Scholar
  8. 8.
    J. Barbier, A. Morales, R. Maurel: Bul. Soc. Chim., I. 31 (1978)Google Scholar
  9. 9.
    J. Benson, M. Boudart: J. Catal.,4, 705 (1965)Google Scholar
  10. 10.
    R. Bacaud, H. Charcosset, M. Guenin, R. Torrecas-Hidalgo, L. Tournayan: Appl. Catal.,1, 81 (1981)Google Scholar
  11. 11.
    J. Barbier, G. Corro, Y. Zhang, J. P. Bournonville, J. P. Franck: Appl. Catal. (in press)Google Scholar

Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • J. Barbier
    • 1
  • E. Churin
    • 1
  • J. M. Parera
    • 2
  • J. Riviere
    • 1
  1. 1.Laboratoire de Catalyse en Chimie OrganiqueUA CNRS 350Poitiers-CedexFrance
  2. 2.INCAPE Santa FeArgentina

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