Skip to main content
Log in

Synthesis of thiolane from tetrahydrofuran and H2S in the presence of proton-donor catalysts

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

In the presence of proton-donor catalysts, at 300–400°C tetrahydrofuran interaction with H2S yields up to 25% thiolane. These catalysts are low-selective and have low stability due to the occurrence of decomposition and polymerization processes.

Abstract

В присутствии протонодонорных катализаторов при 300–400°C тетрагидрофуран взаимодействует с H2S с выходом тиолана до 25%. Катализаторы низкоизбирательны и малоустойчивы вследствие протекания процессов разложения и полимеризации.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Yu. K. Yuriev: Catalysis in Higher School, Part 2. Moscow State University 1962.

  2. Tyong Van Dao, A. A. Kubasov, K. V. Topchieva: Vestnik MGU,2, 146 (1978)

    Google Scholar 

  3. Y. Uno, T. Mory, K. Hatada: Acta Phys. Chem.,24, 233 (1978)

    Google Scholar 

  4. E. A. Paukshtis, E. N. Yurchenko: Usp. Khim.,52, 426 (1983)

    Google Scholar 

  5. I. V. Desyatov, V. N. Yakovleva, A. V. Mashkina: React. Kinet. Catal. Lett.,41, 97 (1990)

    Google Scholar 

  6. L. T. Zhuravlev, A. V. Kiselev: Zh. Fiz. Khim.,39, 453 (1965)

    Google Scholar 

  7. A. V. Mashkina, E. A. Paukshtis, V. N. Yakovleva: Kinet. Katal.,29, 1174 (1988)

    Google Scholar 

  8. L. V. Malysheva: Cand. Thesis, Inst. Catal., Novosibirsk, 1987. 1987.

  9. E. N. Guryanova, I. P. Goldshtein, I. P. Romm: Donor-Acceptor Bond. Khimiya, Moskva 1973.

    Google Scholar 

  10. I. V. Desyatov, E. A. Paukshtis, A. V. Mashkina: React. Kinet. Catal. Lett.,41, 161 (1990)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Desyatov, I.V., Mashkina, A.V. Synthesis of thiolane from tetrahydrofuran and H2S in the presence of proton-donor catalysts. React Kinet Catal Lett 44, 39–44 (1991). https://doi.org/10.1007/BF02068381

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02068381

Keywords

Navigation