Abstract
Photolysis of alkylperoxy radicals with λ≦250 nm light has been studied and proposed for investigation of heterogeneous-homogeneous reactions by freezing out radicals from the gas phase and their ESR identification. Using amine decomposition reaction in the presence of O2 as an example, we have shown that photodissociation of frozen peroxy radicals can be used to reduce the structure of initial alkyl radicals.
Abstract
Для исследования гетерогенно-гомогенных реакций путем вымораживания из газовой фазы и регистрации радикалов методом ЭПР предложен и изучен фотолиз алкилперекисных радикалов светом с λ≦250 нм. На примере реакции разложения аминов в присутствии кислорода показано, что в результате фотодиссоциации вымороженного перекисного радикала можно восстановить структуру исходного алкильного радикала.
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Pak, S.N., Yermolayev, V.K. & Ismagilov, Z.R. Photolysis of alkylperoxy radicals frozen out from the gas phase. React Kinet Catal Lett 32, 429–434 (1986). https://doi.org/10.1007/BF02068347
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DOI: https://doi.org/10.1007/BF02068347