Skip to main content
SpringerLink
Log in

Synthesis of benzothiophenes in gas phase from aromatic hydrocarbons and carbon disulfide

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

A way of synthesis of benzothiophenes, in the gas phase, employing a monosubstituted aromatic compound, carbon disulfide as sulfur source and a Kearby type aluminium orthophosphate as catalyst, has been studied. The best yields in benzothiophene (53%) were reached when vinylbenzene was employed, in a very selective reaction.

Abstract

Изучен способ синтеза бензотиофенов в газовой фазе, используя ароматическое соединение и сероуглерод, как источник серы, на ортофосфате алюминия, как катализаторе типа Кёрбая. Наилучшие вуходы бензотиофена (53%) были достигнуты в очень селективной реакции для винилбензола.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V.P. Litvinov, E.G. Ostapenko: Izv.Akad.Nauk SSSR, Ser. Khim.,8, 1683 (1971)

    Google Scholar 

  2. C. Hansch, W.A. Blondon: J.Am.Chem.Soc.,70, 1561 (1948)

    Google Scholar 

  3. C. Hansch, B. Schmidhalter: J.Org.Chem., 1056 (1955)

  4. F. Azizian, J.S. Pizey: J.Chem.Tech.Biotechnol.,30, 429 (1980)

    Google Scholar 

  5. F. Azizian, J.S. Pizey: J.Chem.Tech.Biotechnol.,30, 648 (1980)

    Google Scholar 

  6. F. Azizian, J.S. Pizey: J.Chem.Tech.Biotechnol.,31, 163 (1981)

    Google Scholar 

  7. S. Esteban, J.M. Marinas, M.P. Martinez-Alcazar, M. Martinez, A.R. Agarrabeitia: Bull.Soc.Chim.Belg., 92, 715 (1983)

    Google Scholar 

  8. S. Esteban, J.M. Marinas, M.P. Martinez-Alcazar, M. Martinez, R.A. Agarrabeitia: An.Quim.,80C, 69 (1984)

    Google Scholar 

  9. J. Alexander, H.G. Shimp: Natl. Petroleum News,36, 31R 537 (1944)

    Google Scholar 

  10. S. Esteban, J.M. Marinas, M.P. Martinez-Alcazar: Afinidad,37, 509 (1980)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Complutense University of Madrid, Ciudad Universitaria, 280040, Madrid

    M. P. Martinez-Alcazar, M. Martinez & A. R. Agarrabeitia

  2. Department of General Chemistry and macromolecules, U.N.E.D., Ciudad Universitaria, 280040, Madrid

    S. Esteban

  3. Department of Organic Chemistry, Faculty of Sciences, University of Córdoba, Avda. Medina Azahara s/n, Cordoba, Spain

    J. M. Marinas

Authors
  1. S. Esteban
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. M. Marinas
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. P. Martinez-Alcazar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Martinez
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. R. Agarrabeitia
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Esteban, S., Marinas, J.M., Martinez-Alcazar, M.P. et al. Synthesis of benzothiophenes in gas phase from aromatic hydrocarbons and carbon disulfide. React Kinet Catal Lett 30, 157–163 (1986). https://doi.org/10.1007/BF02068160

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02068160

Keywords

Search

Navigation