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The UV-VIS spectroscopic study of the interaction between WCl6 and esters of carboxylic acids

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Abstract

The reaction of WCl6 with methyl 10-undecenoate and methyl palmitate has been studied. The rate constant of the first step of the reaction has been established and compared with that of the WCl6+(CH3)4Sn reaction. On the basis of this comparison the influence of the reaction of WCl6 + ester on the ester metathesis is discussed.

Abstract

Исследовали восстановление WCl6 Метил-10-ундеденоатом и метил-палмиатом. Определена константа скорости для первой ступени реакции, которую сравнивали с константой скорости для реакции WCl6+(CH3)4Sn. На основе этого сравнения обсуждается влияние реакции WCl6+эфир на метатезис эфира.

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Authors and Affiliations

  1. J. Heyrovsky Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 121 38, Prague 2

    H. Balcar

  2. Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06, Prague 6

    J. Dybal

Authors
  1. H. Balcar
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  2. J. Dybal
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Balcar, H., Dybal, J. The UV-VIS spectroscopic study of the interaction between WCl6 and esters of carboxylic acids. React Kinet Catal Lett 30, 17–22 (1986). https://doi.org/10.1007/BF02068141

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  • DOI: https://doi.org/10.1007/BF02068141

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