Influences of acid treatments of active carbons on NO reduction over carbon-supported copper oxides
- 44 Downloads
Active carbon supported copper oxides were used in NO reduction. The conversions of NO reduction depends strongly on surface oxygen-containing groups on the active carbons, among them the carboxyls and lactones favored remarkably the NO reduction. However, hydrochloric acid treatment led to the decomposition of the carboxyls and lactones on C2 and C3, decreasing their reactivities for NO reduction. Concentrated HNO3 treatment of active carbon produced higher conversions of NO reduction at relatively low temperatures due to the marked increase in the amounts of the carboxyls and lactones.
KeywordsReduction of NO active carbon
Unable to display preview. Download preview PDF.
- 1.E. Richter:Catal. Today,7, 93 (1990).Google Scholar
- 2.A. Nishijima, Y. Kiyozumi, A. Ueno, M. Kurita, H. Hagiwara, T. Sato, N. Todo:Bull. Chem. Soc. Jpn.,52, 3724 (1979).Google Scholar
- 3.L. Singoredjo, M. Slagt, J. Wees, F. Kapteijn, J.A. Moulijn:Catal.Today,7, 157 (1990).Google Scholar
- 4.T. Grzybek:Fuel,69, 604 (1990).Google Scholar
- 5.T. Grzybek, H. Papp:Appl. Catal., B1, 271 (1992).Google Scholar
- 6.H.P. Boehm:Adv. Catal.,16, 179 (1966).Google Scholar
- 7.J. Kazmierczak, S. Biniak, A. Swiatkowski, K.H. Radeke:J. Chem. Soc., Faraday Trans.,87, 3557 (1991).Google Scholar
- 8.C. Ishizaki, I. Marti:Carbon,19, 409 (1981).Google Scholar