Reaction Kinetics and Catalysis Letters

, Volume 59, Issue 1, pp 145–150 | Cite as

New correlations to analyze isothermal critical phenomena in heterogeneous catalysis reactions (“Critical simplification”, “hysteresis thermodynamics”)

  • Gregory S. Yablonskii
  • Mark Z. Lazman
Article

Abstract

The analytical expressions for all kinetic hysteresis branches were obtained by means of the kinetic polynomial technique.

Keywords

Critical phenomena in catalysis CO oxidation hysteresis 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    G. S. Yablonskii, V. I. Bykov, A. N. Gorban, V. I. Elokhin:Comprehensive Chemical Kinetics, Vol. 32,Kinetic Models of Catalytic Reactions, Chapt. 5,6. Ed. R. J. Compton, p. 392. Elsevier, Amsterdam 1991.Google Scholar
  2. 2.
    G. S. Yablonskii, V. I. Bykov, A. N. Gorban:Kinetic Models of Catalytic Reactions, p. 253. Nauka, Novosibirsk 1983.Google Scholar
  3. 3.
    G. S. Yablonskii, V. I. Bykov, V. I. Elokhin:Kinetics of Model Reactions of Heterogeneous Catalysis, p. 222. Nauka, Novosibirsk 1984.Google Scholar
  4. 4.
    M. Z. Lazman, V. I. Bykov, G. S. Yablonskii:Khim. Fiz.,2, 239 (1983).Google Scholar
  5. 5.
    M. Z. Lazman, V. I. Bykov, G. S. Yablonskii:Khim. Fiz.,2, 413 (1983).Google Scholar
  6. 6.
    M. Z. Lazman, L. N. Romanov, G. S. Yablonskii:Khim. Fiz.,4, 691 (1985).Google Scholar
  7. 7.
    G. S. Yablonskii, M. Z. Lazman, V. I. Bykov:Dokl. Akad Nauk SSSR,269, 166 (1983).Google Scholar
  8. 8.
    M. Z. Lazman, G. S. Yablonskii:Patterns and Dynamics in Reactive Media, p. 117. IMA Proc. 1989 — Springer Verlag 1991.Google Scholar
  9. 9.
    H. J. Wei, P. R. Norton:J. Chem. Phys.,89, 1170 (1988).Google Scholar
  10. 10.
    M. Ehsasi, J. H. Block: inProc. of Intern. Conf. Unsteady-State Processes in Catalysis, 5–8 June 1990, Novosibirsk. Ed. by Yu. Sh. Matros, VSP-VIII, p. 47. Netherlands 1990.Google Scholar
  11. 11.
    Yu. I. Pyatnitskii, I. A. Ostapyuk:Teor. Eksp. Khim.,22, 83 (1986).Google Scholar
  12. 12.
    V. V. Gorodetskii, V. A. Sobyanin, A. R. Cholach, M. Yu., Smirnov: inProc. 8th Intern. Congr. on Catalysis, p. 323. Berlin 1984.Google Scholar
  13. 13.
    V. A. Sobyanin, G. K. Boreskov, A. R. Cholach:Dokl. Akad Nauk SSSR,279, 1410 (1984).Google Scholar
  14. 14.
    M. Z. Lazman, G. S. Yablonskii, V. A. Sobyanin:Kinet. Katal.,27, 67 (1986).Google Scholar

Copyright information

© Akadémiai Kiadó 1996

Authors and Affiliations

  • Gregory S. Yablonskii
    • 1
  • Mark Z. Lazman
    • 2
  1. 1.Kiev Polytechnical InstituteKievUkraine
  2. 2.Hyprotech Ltd.CalgaryCanada

Personalised recommendations